ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE

Rui-rui Yue a; Jing-kun Xu a; Bao-yang Lu a; Cong-cong Liu a; Zhao-jin Zhu a; Zhuo Zhang b

doi:10.1007/s10118-010-9141-7

Your Location：

Home >

Browse articles >

ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE

Papers | Updated：2021-06-21

- ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE
- Vol. 28, Issue 5, Pages: 771-780(2010)
- Affiliations：
- Author bio：
- Funds：
- DOI：10.1007/s10118-010-9141-7
  CLC：
- Published：20 September 2010
- Accepted：
Scan QR Code
Rui-rui Yue a, Jing-kun Xu a, Bao-yang Lu a, et al. ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE[J]. 2010, 28(5): 771-780.
DOI：

Rui-rui Yue a, Jing-kun Xu a, Bao-yang Lu a, et al. ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE[J]. 2010, 28(5): 771-780. DOI： 10.1007/s10118-010-9141-7.

摘要

Poly(benzanthrone-co-thiophene)

a new conducting copolymer

was successfully prepared by direct anodic oxidation of benzanthrone and thiophene (Th) in a binary solvent system containing boron trifluoride diethyl etherate (BFEE) and acetonitrile (ACN). The as-formed copolymer film electrodeposited with monomer feed ratio of benzanthrone/Th = 1:1 at the applied potential of 1.3 V versus Ag/AgCl exhibited the advantages of both polybenzanthrone and polythiophene

such as active electrochemical behavior

excellent thermal stability

relatively high electrical conductivity and mechanical properties. UV-Vis spectroscopy

1H-NMR and SEM were used to characterize and investigate the structures and morphologies of the copolymers. Fluorescence spectroscopy studies revealed that the obtained copolymer films show strong emission at about 525 nm. Moreover

the emitting properties of the copolymers could be tuned by changing some parameters during the electropolymerization process

such as monomer feed ratio.

Abstract

Poly(benzanthrone-co-thiophene)

a new conducting copolymer

such as active electrochemical behavior

excellent thermal stability

relatively high electrical conductivity and mechanical properties. UV-Vis spectroscopy

the emitting properties of the copolymers could be tuned by changing some parameters during the electropolymerization process

such as monomer feed ratio.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature

Advances in Polymer-based Circularly Polarized Luminescent Materials

Bioinspired Zinc-doped Nano Hydroxyapatite Reinforced Poly(lactic acid) Composites for Bone Repair

Molecularly Engineered Polyimide Films with Switchable Cavitation for Bidirectional Passive Thermal Regulation

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Related Author

No data

Related Institution

No data

⁰