STABILITY AND ELECTROCHEMICAL PROPERTIES OF FULL-CONJUGATED SELF-ASSEMBLED FILMS BASED ON POLYANILINE AND ITS ACID-SUBSTITUTED DERIVATES

Miao-miao Xiao a; Bin Tong a; Wei Zhao a; Jian-bing Shi a; Yue-xiu Pan a; Jin-bo Shen a; Jun-ge Zhi b; Yu-ping Dong a

doi:10.1007/s10118-010-9014-0

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STABILITY AND ELECTROCHEMICAL PROPERTIES OF FULL-CONJUGATED SELF-ASSEMBLED FILMS BASED ON POLYANILINE AND ITS ACID-SUBSTITUTED DERIVATES

Papers | Updated：2021-06-21

- STABILITY AND ELECTROCHEMICAL PROPERTIES OF FULL-CONJUGATED SELF-ASSEMBLED FILMS BASED ON POLYANILINE AND ITS ACID-SUBSTITUTED DERIVATES
- Vol. 28, Issue 3, Pages: 331-336(2010)
- Affiliations：
- Author bio：
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- DOI：10.1007/s10118-010-9014-0
  CLC：
- Published：20 May 2010
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Miao-miao Xiao a, Bin Tong a, Wei Zhao a, et al. STABILITY AND ELECTROCHEMICAL PROPERTIES OF FULL-CONJUGATED SELF-ASSEMBLED FILMS BASED ON POLYANILINE AND ITS ACID-SUBSTITUTED DERIVATES[J]. 2010, 28(3): 331-336.
DOI：

Miao-miao Xiao a, Bin Tong a, Wei Zhao a, et al. STABILITY AND ELECTROCHEMICAL PROPERTIES OF FULL-CONJUGATED SELF-ASSEMBLED FILMS BASED ON POLYANILINE AND ITS ACID-SUBSTITUTED DERIVATES[J]. 2010, 28(3): 331-336. DOI： 10.1007/s10118-010-9014-0.

摘要

The stability of full-conjugated self-assembled (SA) multilayer films based on partially doped polyaniline (PANI) as a polycation and poly(o-aminobenzoic acid) (PCAN)

poly(aniline-2-sulfonic acid) (PSAN) as polyanions is investigated in alkali aqueous solutions. The self-assembled PANI-PCAN films keep their stability within 24 h in 1 mol/L NaOH solution

the PANI-PSAN films

however

maintain the stability for 20 min in the same condition because the solubility of PSAN in alkali solutions is much higher than that of PCAN. The electrochemical properties of the SA films are determined

and the film-CdS composites formed in situ are also reported.

Abstract

The stability of full-conjugated self-assembled (SA) multilayer films based on partially doped polyaniline (PANI) as a polycation and poly(o-aminobenzoic acid) (PCAN)

poly(aniline-2-sulfonic acid) (PSAN) as polyanions is investigated in alkali aqueous solutions. The self-assembled PANI-PCAN films keep their stability within 24 h in 1 mol/L NaOH solution

the PANI-PSAN films

however

and the film-CdS composites formed in situ are also reported.

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