SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES

Ibrahim Erol; Cemal Cifci

doi:10.1007/s10118-010-1005-7

Your Location：

Home >

Browse articles >

SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES

Paper | Updated：2021-06-21

- SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES
- Chinese Journal of Polymer Science Vol. 29, Issue 1, Pages: 101-110(2011)
- Affiliations：
  
  Department of Chemistry, Faculty of Arts and Science, University of Afyon Kocatepe, Afyonkarahisar, Turkey
- Author bio：
  
  *Ibrahim Erol, E-mail: iberol@hotmail.com; ierol@aku.edu.tr
- Funds：
- DOI：10.1007/s10118-010-1005-7
  CLC：
- Received：30 December 2009，
  
  Revised：2010-02-08，
  
  Accepted：01 March 2010，
  
  Published：2011
- Accepted：
Scan QR Code
Ibrahim Erol, Cemal Cifci. SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES[J]. Chinese Journal of Polymer Science, 2011, 29(1): 101-110.
DOI：

Ibrahim Erol, Cemal Cifci. SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES[J]. Chinese Journal of Polymer Science, 2011, 29(1): 101-110. DOI： 10.1007/s10118-010-1005-7.

摘要

Abstract

A new type of methacrylate monomer

2-(4-benzoylphenoxy)-2-oxoethyl methylacrylate (BOEMA) was synthesized. The radical homopolymerization of BOEMA was performed at 65℃ in a 1

4-dioxane solution with benzoyl peroxide as an initiator. The oxime and thiosemicarbazone derivatives of poly[2-(4-benzoylphenoxy)-2-oxoethyl methylacrylate] poly(BOEMA) were prepared with hydroxylamine hydrochloride

and thiosemicarbazone hydrochloride

respectively. The monomer and its homopolymer were characterized with Fourier transform infrared and NMR techniques. The thermal stabilities of poly(BOEMA) and its derivatives were investigated with thermogravimetric analysis and differential scanning calorimetry. The ultraviolet stability of the polymers was compared. The antibacterial and antifungal effects of the monomer and the polymer and its derivatives were also investigated on various bacteria and fungi. The activation energies of the thermal degradation of the polymers were calculated with the Ozawa and Kissinger methods.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Modulating Molecular Weight of Polyethylenes from Oligomer to Polymer Using Highly Thermal Stable Cationic α-Diimine Palladium Complexes

Effect of Graphene/Nickel-iron Layered Double Hydroxide Hybrids on the Thermal Decomposition and Flame Retardancy of Acrylonitrile-butadiene-styrene Copolymer Composites

Inorganic Thermoplastic Flame Retardant as a Basic Component of Low-combustible Polymer Blends

Methyl Groups Pendant on Triphenylmethane Toward Modulating Thermal Stability and Dielectric Properties of the Crosslinkable Fluorinated Polyimide Films with High Transparency

pH-Responsive L-Cysteine-conjugated Polydopamine Nanocarriers for Controlled Release of Emamectin Benzoate against Pieris brassicae

Related Author

Feng-Bin Liu

Chun-Yu Zhang

Xue-Quan Zhang

Heng Liu

Xiao-Hua Wang

Ning-Ning Hong

Jing-Ping Liu

Xin Wang

Related Institution

State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, Key Laboratory of Rubber-Plastics, Ministry of Education, School of Polymer Science and Engineering, Qingdao University of Science & Technology

State Key Laboratory of Fire Science, University of Science and Technology of China

State Key Laboratory of High-Efficiency Special Cable Technology, Shanghai Electric Cable Research Institute Co., Ltd.

Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences

Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences

⁰