Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends

Kang-Jing Zhang; Zhao-Bin Qiu

doi:10.1007/S10118-019-2269-1

Your Location：

Home >

Browse articles >

Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends

ARTICLE | Updated：2021-02-18

- Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends
- Chinese Journal of Polymer Science Vol. 37, Issue 11, Pages: 1169-1175(2019)
- Affiliations：
  
  State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  qiuzb@mail.buct.edu.cn
- Funds：
- DOI：10.1007/S10118-019-2269-1
  CLC：
- Received：11 March 2019，
  
  Revised：2019-4-2，
  
  Accepted：04 April 2019，
  
  Online First：24 May 2019，
  
  Published：2019-11
- Accepted：
Scan QR Code
Zhang, K. J.; Qiu, Z. B. Miscibility and crystallization behavior of novel branched poly(ethylene succinate)/poly(vinyl phenol) blends. Chinese J. Polym. Sci. 2019, 37, 1169–1175.

Kang-Jing Zhang, Zhao-Bin Qiu. Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1169-1175.
Zhang, K. J.; Qiu, Z. B. Miscibility and crystallization behavior of novel branched poly(ethylene succinate)/poly(vinyl phenol) blends. Chinese J. Polym. Sci. 2019, 37, 1169–1175. DOI： 10.1007/S10118-019-2269-1.

Kang-Jing Zhang, Zhao-Bin Qiu. Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1169-1175. DOI： 10.1007/S10118-019-2269-1.

摘要

Abstract

The blends of novel branched poly(ethylene succinate) (b-PES) and poly(vinyl phenol) (PVPh) were prepared

via

a solution and casting method. The miscibility

melting behavior

spherulitic morphology and growth

and crystal structure of b-PES/PVPh blends were investigated in detail. PVPh was miscible with b-PES over the whole compositions as evidenced by the single composition dependent glass transition temperature. Double melting behavior occurred in neat b-PES and b-PES/PVPh 85/15 blend after isothermal melt crystallization

which may be explained by the melting

recrystallization

and remelting mechanism. In addition

the depression of equilibrium melting point of an 85/15 blend was also found

confirming again the miscibility between the two components. The addition of PVPh caused the decrease of nucleation density and crystal growth rates of b-PES spherulites in the blend. The crystal structure of b-PES was unchanged before and after blending; moreover

the crystallinity of b-PES decreased slightly in the blend.

关键词

Keywords

references

Zeng, J.; Wu, F.; Huang, C.; He, Y.; Wang, Y . Urethane ionic groups induced rapid crystallization of biodegradable poly(ethylene succinate) . ACS Macro Lett. , 2012 . 1 965 - 968 . DOI: 10.1021/mz300243t http://doi.org/10.1021/mz300243t .

Tezuka, Y.; Ishii, N.; Kasuya, K.; Mitomo, H . Degradation of poly(ethylene succinate) by mesophilic bacteria . Polym. Degrad. Stab. , 2004 . 84 115 - 121 . DOI: 10.1016/j.polymdegradstab.2003.09.018 http://doi.org/10.1016/j.polymdegradstab.2003.09.018 .

Gan, Z.; Abe, H.; Doi, Y . Biodegradable poly(ethylene succinate) (PES). 2. Crystal morphology of melt-crystallized ultrathin film and its change after enzymatic degradation . Biomacromolecules , 2000 . 1 713 - 720 . DOI: 10.1021/bm000055t http://doi.org/10.1021/bm000055t .

Qiu, Z.; Fujinnami, S.; Komura, M.; Nakajima, K.; Ikehara, T.; Nishi, T . Nonisothermal crystallization kinetics of poly(butylene succinate) and poly(ethylene succinate) . Polym. J. , 2004 . 36 642 - 646 . DOI: 10.1295/polymj.36.642 http://doi.org/10.1295/polymj.36.642 .

Gan, Z.; Abe, H.; Doi, Y . Biodegradable poly(ethylene succinate) (PES). 1. Crystal growth kinetics and morphology . Biomacromolecules , 2000 . 1 704 - 712 . DOI: 10.1021/bm0000541 http://doi.org/10.1021/bm0000541 .

Qiu, Z.; Komura, M.; Ikehara, T.; Nishi, T . DSC and TMDSC study of melting behavior of poly(butylene succinate) and poly(ethylene succinate) . Polymer , 2003 . 44 7781 - 7785 . DOI: 10.1016/j.polymer.2003.10.045 http://doi.org/10.1016/j.polymer.2003.10.045 .

Kataoka, T.; Abe, T.; Ikehara, T . Crystalline layered morphology in the phase-separated blend of poly(butylene succinate) and poly(ethylene succinate) . Polym. J. , 2015 . 47 645 - 648 . DOI: 10.1038/pj.2015.46 http://doi.org/10.1038/pj.2015.46 .

Liu, X.; Zhu, J.; Ni, H.; Chen, S . Influence of blend composition on crystallization of poly(L-lactic acid)/poly(ethylene oxide) crystalline/crystalline blends . J. Macromol. Sci. , 2015 . 54 203 - 241 . DOI: 10.1080/00222348.2014.996478 http://doi.org/10.1080/00222348.2014.996478 .

Zeng, J.; Zhu, Q.; Li, Y.; Qiu, Z.; Wang, Y . Unique crystalline/crystalline polymer blends of poly(ethylene succinate) and poly( p -dioxanone): Miscibility and crystallization behaviors . J. Phys. Chem. B , 2010 . 114 14827 - 14833 . DOI: 10.1021/jp104709z http://doi.org/10.1021/jp104709z .

He, Y.; Zeng, J.; Li, S.; Wang, Y . Crystallization behavior of partially miscible biodegradable poly(butylene succinate)/poly(ethylene succinate) blends . Thermochim. Acta , 2012 . 529 80 - 86 . DOI: 10.1016/j.tca.2011.11.031 http://doi.org/10.1016/j.tca.2011.11.031 .

Kataoka, T.; Hiramoto, K.; Kurihara, H.; Ikehara, T . Effects of melt annealing on the miscibility and crystallization of poly(butylene succinate)/poly(ethylene succinate) blends . Polym. J. , 2014 . 46 405 - 411 . DOI: 10.1038/pj.2014.11 http://doi.org/10.1038/pj.2014.11 .

Lu, J.; Qiu, Z.; Yang, W . Fully biodegradable blends of poly(L-lactide) and poly(ethylene succinate): Miscibility, crystallization, and mechanical properties . Polymer , 2007 . 48 4196 - 4204 . DOI: 10.1016/j.polymer.2007.05.035 http://doi.org/10.1016/j.polymer.2007.05.035 .

Papageorgiou, G.; Bikiaris, D . Synthesis and properties of novel biodegradable/biocompatible poly[propylene- co -(ethylene succinate)] random copolyesters . Macromol. Chem. Phys. , 2009 . 210 1408 - 1421 . DOI: 10.1002/macp.v210:17 http://doi.org/10.1002/macp.v210:17 .

Chen, M.; Chang, W.; Lu, H.; Chen, C.; Peng, J.; Tsai, C . Characterization, crystallization kinetics and melting behavior of poly(ethylene succinate) copolyester containing 5 mol% trimethylene succinate . Polymer , 2007 . 48 5408 - 5416 . DOI: 10.1016/j.polymer.2007.06.060 http://doi.org/10.1016/j.polymer.2007.06.060 .

Chen, C.; Lu, H.; Chen, M.; Peng, J.; Tsai, C.; Yang, C . Synthesis and characterization of poly(ethylene succinate) and its copolyesters containing minor amounts of butylene succinate . J. Appl. Polym. Sci. , 2009 . 111 14333 - 1439 . .

Yang, Y.; Qiu, Z . Crystallization and melting behavior of biodegradable poly(ethylene succinate- co -6 mol% butylene succinate) . J. Appl. Polym. Sci. , 2011 . 122 105 - 111 . DOI: 10.1002/app.v122.1 http://doi.org/10.1002/app.v122.1 .

Li, X.; Qiu, Z . Crystallization kinetics, morphology, and mechanical properties of novel poly(ethylene succinate- co -octamethylene succinate) . Polym. Test. , 2015 . 48 125 - 132 . DOI: 10.1016/j.polymertesting.2015.10.002 http://doi.org/10.1016/j.polymertesting.2015.10.002 .

Li, X.; Qiu, Z . Synthesis and properties of novel poly(ethylene succinate- co -decamethylene succinate) copolymers . RSC Adv. , 2015 . 5 103713 - 103721 . DOI: 10.1039/C5RA23585E http://doi.org/10.1039/C5RA23585E .

Wu, H.; Qiu, Z . Synthesis, crystallization kinetics and morphology of novel poly(ethylene succinate- co -ethylene adipate) copolymers . CrystEngComm , 2012 . 14 3586 - 3595 . DOI: 10.1039/c2ce06629g http://doi.org/10.1039/c2ce06629g .

Qiu, S.; Su, Z.; Qiu, Z . Crystallization kinetics, morphology and mechanical properties of novel biodegradable poly(ethylene succinate- co -ethylene suberate) copolyesters . Ind. Eng. Chem. Res. , 2016 . 55 10286 - 10293 . DOI: 10.1021/acs.iecr.6b02654 http://doi.org/10.1021/acs.iecr.6b02654 .

Jin, H.; Kim, D.; Kim, M.; Lee, I.; Lee, H.; Yoon, J . Synthesis and properties of poly(butylene succinate) with n -hexenyl side branches . J. Appl. Polym. Sci. , 2001 . 81 2219 - 2226 . DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

Yan, D.; Wang, W.; Zhu, S . Effect of long chain branching on rheological properties of metallocene polyethylene . Polymer , 1999 . 40 1737 - 1744 . DOI: 10.1016/S0032-3861(98)00318-8 http://doi.org/10.1016/S0032-3861(98)00318-8 .

Gao, R.; He, X.; Shao, Y.; Hu, Y.; Zhang, H.; Liu, Z.; Liu, B . Effects of branch content and branch length on polyethylene crystallization: Molecular dynamics simulation . Macromol. Theor. Simul. , 2016 . 25 303 - 311 . DOI: 10.1002/mats.201500089 http://doi.org/10.1002/mats.201500089 .

Zheng, Y.; Tee, H.; Wei, Y.; Wu, X.; Mezger, M.; Yan, S.; Landfester, K.; Wagener, K.; Wurm, F.; Lieberwirth, I . Morphology and thermal properties of precision polymers: The crystallization of butyl branched polyethylene and polyphosphoesters . Macromolecules , 2016 . 49 1321 - 1330 . DOI: 10.1021/acs.macromol.5b02581 http://doi.org/10.1021/acs.macromol.5b02581 .

Marie, V.; Nicolas, J.; Rene, S.; Nadege, B.; Christian, C.; Alain, R.; Francoise, F . Synthesis of branched poly(butylene succinate): Structure properties relationship . Chinese J. Polym. Sci. , 2016 . 34 873 - 888 . DOI: 10.1007/s10118-016-1805-5 http://doi.org/10.1007/s10118-016-1805-5 .

Qiu, S.; Zhang, K.; Su, Z.; Qiu, Z . Thermal behavior, mechanical and rheological properties, and hydrolytic degradation of novel branched biodegradable poly(ethylene succinate) copolymers . Polym. Test. , 2018 . 66 64 - 69 . DOI: 10.1016/j.polymertesting.2018.01.008 http://doi.org/10.1016/j.polymertesting.2018.01.008 .

Kuo, S.; Huang, C.; Chang, F . Study of hydrogen-bonding strength in poly( ε -caprolactone) blends by DSC and FTIR . J. Polym. Sci., Part B: Polym. Phys. , 2001 . 39 1348 - 1359 . DOI: 10.1002/(ISSN)1099-0488 http://doi.org/10.1002/(ISSN)1099-0488 .

Zhang, L.; Goh, S.; Lee, S . Miscibility and crystallization behaviour of poly(L-lactide)/poly( p -vinyl phenol) blends . Polymer , 1998 . 39 4841 - 4847 . DOI: 10.1016/S0032-3861(97)10167-7 http://doi.org/10.1016/S0032-3861(97)10167-7 .

Qiu, Z.; Komura, M.; Ikehara, T.; Nishi, T . Poly(butylene succinate)/poly(vinyl phenol) blends. Part 1. Miscibility and crystallization . Polymer , 2003 . 44 8111 - 8117 . DOI: 10.1016/j.polymer.2003.10.030 http://doi.org/10.1016/j.polymer.2003.10.030 .

Qiu, Z.; Fujinami, S.; Komura, M.; Nakajima, K.; Ikehara, T.; Nishi, T . Miscibility and crystallization of poly(ethylene succinate)/poly(vinyl phenol) blends . Polymer , 2004 . 45 4515 - 4521 . DOI: 10.1016/j.polymer.2004.04.033 http://doi.org/10.1016/j.polymer.2004.04.033 .

Yang, F.; Qiu, Z.; Yang, W . Miscibility and crystallization of biodegradable poly(butylene succinate- co -butylene adipate)/poly(vinyl phenol) blends . Polymer , 2009 . 50 2328 - 2333 . DOI: 10.1016/j.polymer.2009.03.029 http://doi.org/10.1016/j.polymer.2009.03.029 .

Cai, H.; Yu, J.; Qiu, Z . Miscibility and crystallization of biodegradable poly(3-hydroxybutyrate- co -3-hydroxyhexanoate)/poly(vinyl phenol) blends . Polym. Eng. Sci. , 2012 . 52 233 - 241 . DOI: 10.1002/pen.v52.2 http://doi.org/10.1002/pen.v52.2 .

Weng, M.; Qiu, Z . Crystallization kinetics and morphology of novel miscible crystalline/amorphous polymer blends of biodegradable poly(butylene succinate- co -butylene carbonate) and poly(vinyl phenol) . Ind. Eng. Chem. Res. , 2013 . 52 10198 - 10205 . DOI: 10.1021/ie401745e http://doi.org/10.1021/ie401745e .

Shi, X.; Qiu, Z . Miscibility, crystallization behavior and morphology of novel poly(butylene suberate) and poly(vinyl phenol) blends . RSC Adv. , 2015 . 5 79691 - 79698 . DOI: 10.1039/C5RA16801E http://doi.org/10.1039/C5RA16801E .

Hou, Y.; Wu, Q.; Chen, T.; Sun, P . Unique evolution of spatial and dynamic heterogeneities on the glass transition behavior of PVPh/PEO blends . Chinese J. Polym. Sci. , 2012 . 30 900 - 915 . DOI: 10.1007/s10118-012-1182-7 http://doi.org/10.1007/s10118-012-1182-7 .

Fox, T . Influence of diluent and copolymer composition on the glass transition temperature of a polymer system . Bull. Am. Phys. Soc. , 1956 . 1 123 .

Penning, J.; Manley, R . Miscible blends of two crystalline polymers. 1. Phase behavior and miscibility in blends of poly(vinylidene fluoride) and poly(1,4-butylene adipate) . Macromolecules , 1996 . 29 77 - 83 . DOI: 10.1021/ma950651t http://doi.org/10.1021/ma950651t .

Flory, P. Principles of polymer chemistry . Cornell University Press, Ithaca, NY, 1953 .

Nishi, T.; Wang, T . Melting point depression and kinetic effects of cooling on crystallization in poly(vinylidene fluoride)-poly(methyl methacrylate) mixtures . Macromolecules , 1975 . 8 909 - 915 . DOI: 10.1021/ma60048a040 http://doi.org/10.1021/ma60048a040 .

Liu, T.; Petermann, J . Multiple melting behavior in isothermally cold-crystallized isotactic polystyrene . Polymer , 2001 . 42 6453 - 6461 . DOI: 10.1016/S0032-3861(01)00173-2 http://doi.org/10.1016/S0032-3861(01)00173-2 .

Qiu, Z.; Ikehara, T.; Nishi, T . Melting behaviour of poly(butylene succinate) in miscible blends with poly(ethylene oxide) . Polymer , 2003 . 44 3095 - 3099 . DOI: 10.1016/S0032-3861(03)00216-7 http://doi.org/10.1016/S0032-3861(03)00216-7 .

Wu, H.; Qiu, Z . A comparative study of crystallization, melting behavior, and morphology of biodegradable poly(ethylene adipate) and poly(ethylene adipate- co -5 mol% ethylene succinate) . Ind. Eng. Chem. Res. , 2012 . 51 13323 - 13328 . DOI: 10.1021/ie301968f http://doi.org/10.1021/ie301968f .

Hoffman, J.; Weeks, J . X-ray study of isothermal thickening of lamellae in bulk polyethylene at the crystallization temperature . J. Chem. Phys. , 1965 . 42 4301 - 4302 . DOI: 10.1063/1.1695935 http://doi.org/10.1063/1.1695935 .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Inorganic Thermoplastic Flame Retardant as a Basic Component of Low-combustible Polymer Blends

A Unified Approach to Phase Equilibria in Multi-component Polymer Systems with Effective Chemical Potential

Compatibilizer-aided Fabrication of a 'High-entropy Polymer Blend'

The Crystallization Behavior of L-Poly(lactic acid)/Polypropylene Blends: The Acceleration for Both L-Poly(lactic acid) and Polypropylene

Enhanced Segment Mobility Promotes Stereocomplex Crystallization in Polymer Blends via Elevated Segmental Miscibility

Related Author

Viktor A. Novikov

Elena V. Stegno

Andrey V. Grachev

Ali D. Aliev

Victor Yu. Bychkov

Irina O. Plyusnina

Uliana V. Nikulova

Aleksey V. Shapagin

Related Institution

Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences

Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences

State Key Laboratory of Molecule Engineering of Polymers, Department of Macromolecular Science, Fudan University

Shandong Runde Composite Materials Co., Ltd.

State Key Laboratory of Organic-Inorganic Composites & Beijing Key Laboratory of Advanced Functional Polymer Composites, Beijing University of Chemical Technology

⁰