Orientation Efforts as Regulatory Factor of Structure Formation in Permeable Porous Poly(vinylidene fluoride) Films

G. K. Elyashevich; I. S. Kuryndin; I. Yu. Dmitriev; V. K. Lavrentyev; N. N. Saprykina; V. Bukošek

doi:10.01007/s10118-019-2284-2

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Orientation Efforts as Regulatory Factor of Structure Formation in Permeable Porous Poly(vinylidene fluoride) Films

ARTICLE | Updated：2021-02-18

- Orientation Efforts as Regulatory Factor of Structure Formation in Permeable Porous Poly(vinylidene fluoride) Films
- Chinese Journal of Polymer Science Vol. 37, Issue 12, Pages: 1283-1289(2019)
- Affiliations：
  
  a.Institute of Macromolecular Compounds, Russian Academy of Sciences, Bolshoi pr. 31, St. Petersburg 199004, Russia
  b.Faculty for Natural Sciences and Engineering, University of Ljubljana, Snežniška c. 5, Ljubljana 1000, Slovenia
- Author bio：
  
  elya@hq.macro.ru
- Funds：
- DOI：10.01007/s10118-019-2284-2
  CLC：
- Received：12 March 2019，
  
  Revised：2019-4-24，
  
  Accepted：25 April 2019，
  
  Online First：24 June 2019，
  
  Published：2019-12
- Accepted：
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Elyashevich, G. K.; Kuryndin, I. S.; Dmitriev, I. Y.; Lavrentyev, V. K.; Saprykina, N. N.; Bukošek, V. Orientation efforts as regulatory factor of structure formation in permeable porous poly(vinylidene fluoride) films. Chinese J. Polym. Sci. 2019, 37, 1283–1289.

G. K. Elyashevich, I. S. Kuryndin, I. Yu. Dmitriev, et al. Orientation Efforts as Regulatory Factor of Structure Formation in Permeable Porous Poly(vinylidene fluoride) Films[J]. Chinese Journal of Polymer Science, 2019, 37(12): 1283-1289.
Elyashevich, G. K.; Kuryndin, I. S.; Dmitriev, I. Y.; Lavrentyev, V. K.; Saprykina, N. N.; Bukošek, V. Orientation efforts as regulatory factor of structure formation in permeable porous poly(vinylidene fluoride) films. Chinese J. Polym. Sci. 2019, 37, 1283–1289. DOI： 10.01007/s10118-019-2284-2.

G. K. Elyashevich, I. S. Kuryndin, I. Yu. Dmitriev, et al. Orientation Efforts as Regulatory Factor of Structure Formation in Permeable Porous Poly(vinylidene fluoride) Films[J]. Chinese Journal of Polymer Science, 2019, 37(12): 1283-1289. DOI： 10.01007/s10118-019-2284-2.

摘要

Abstract

The manufacturing process of poly(vinylidene fluoride) microporous films containing through flow channels and permeable to liquids has been elaborated. The process is based on polymer melt extrusion with subsequent stages of annealing

uniaxial extensions (" cold” and " hot” drawing)

and thermal stabilization. The effect of orientation parameters (melt draw ratio and extension degrees) on overall porosity

permeability

morphology

and content of polar piezoactive

-phase in crystalline structure of the films was investigated by filtration porosimetry

sorptometry

scanning electron microscopy

X-ray scattering

and mechanical properties measurements. It is shown that the through pores were formed by a percolation mechanism. It is observed that permeability and the

-phase content increased with the growth of extension degree at the pore formation stages but the portion of

-crystallites decreased with increasing melt draw ratio at extrusion

which permitted to regulate the combination of through permeability and piezoactivity values by variation of the preparation process parameters.

关键词

Keywords

references

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