SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S

Your Location：

Home >

Browse articles >

SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S

Rapid Communication | Updated：2021-06-21

- SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S
- Issue 2, Pages: 119-122(2007)
- Affiliations：
  
  1.   Department of Chemistry The Hong Kong University of Science & Technology
  2.   Clear Water Bay
  3.   Kowloon
  4.   China
- Author bio：
- Funds：
  
  This work was partially supported by the Research Grants Council of Hong Kong（Nos. 602706, HKU2/05C, 603505,603304, and 664903）.()
- DOI：
  CLC： TQ317
- Published：2007
- Accepted：
Scan QR Code
[1]Jacky W.Y.Lam,Kevin K.L.Cheuk.SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY(PHENYLACETYLENE)S[J].Chinese Journal of Polymer Science,2007(02):119-122.

SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S[J]. 2007, (2): 119-122.
[1]Jacky W.Y.Lam,Kevin K.L.Cheuk.SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY(PHENYLACETYLENE)S[J].Chinese Journal of Polymer Science,2007(02):119-122. DOI：

SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S[J]. 2007, (2): 119-122. DOI：

摘要

<正>Poly（phenylacetylene）s bearing monosaccharide pendant groups are synthesized in high yields by [Rh（nbd）Cl]2 catalyst. The polymers have high molecular weights and give satisfactory spectroscopic data corresponding to their molecular structures. They are thermally quite stable （≥300℃） and show strong circular dichroism signals in the visible spectral region owing to the helicity of the polyene backbone. The monosaccharide-containing polyacetylenes are cytophilic and can stimulate the growth of living cells.

Abstract

Poly（phenylacetylene）s bearing monosaccharide pendant groups are synthesized in high yields by [Rh（nbd）Cl]2 catalyst. The polymers have high molecular weights and give satisfactory spectroscopic data corresponding to their molecular structures. They are thermally quite stable （≥300℃） and show strong circular dichroism signals in the visible spectral region owing to the helicity of the polyene backbone. The monosaccharide-containing polyacetylenes are cytophilic and can stimulate the growth of living cells.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast

On-demand Peelable UV-curable Adhesives with Superior Bonding Strength: Rational Molecular Engineering of Cohesion-adhesion Synergy

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid

Manipulating Hierarchical Aggregation Structure via Film-forming Kinetics Enables Organic Photovoltaics over 20% Efficiency

Optically Active Helical Poly(phenyl isocyanide)s Bearing Achiral Benzanilide Pendants: from Controlled Synthesis to Enantioseparation Application

Related Author

No data

Related Institution

No data

⁰