RING-OPENING POLYMERIZATION OFε-CAPROLACTONE USING LANTHANIDE TRIS（N-PHENYL-3,5-DI-T-BUTYLSALICYLALDIMINATO）S AS SINGLE COMPONENT CATALYST

Your Location：

Home >

Browse articles >

RING-OPENING POLYMERIZATION OFε-CAPROLACTONE USING LANTHANIDE TRIS（N-PHENYL-3,5-DI-T-BUTYLSALICYLALDIMINATO）S AS SINGLE COMPONENT CATALYST

Note | Updated：2021-06-21

- RING-OPENING POLYMERIZATION OFε-CAPROLACTONE USING LANTHANIDE TRIS（N-PHENYL-3,5-DI-T-BUTYLSALICYLALDIMINATO）S AS SINGLE COMPONENT CATALYST
- Issue 5, Pages: 541-544(2007)
- Affiliations：
  
  1.   Institute of Polymer Science Key Laboratory of Macromolecule Synthesis and Functionalization Ministry of Education
  2.   Zhejiang University
  3.   Hangzhou 310027
  4.   China
- Author bio：
- Funds：
  
  This work was financially supported by the Key Program of National Natural Science Foundation of China（No.G 20434020）();the Special Funds for Major Basic Research Projects（No.G 2005 CB623802）();the Committee of Science and Technology of Zhejiang Province.()
- DOI：
  CLC： TQ316.341
- Published：2007
- Accepted：
Scan QR Code
[1]沈之荃.RING-OPENING POLYMERIZATION OFε-CAPROLACTONE USING LANTHANIDE TRIS(N-PHENYL-3,5-DI-T-BUTYLSALICYLALDIMINATO)S AS SINGLE COMPONENT CATALYST[J].Chinese Journal of Polymer Science,2007(05):541-544.

RING-OPENING POLYMERIZATION OFε-CAPROLACTONE USING LANTHANIDE TRIS（N-PHENYL-3,5-DI-T-BUTYLSALICYLALDIMINATO）S AS SINGLE COMPONENT CATALYST[J]. 2007, (5): 541-544.
[1]沈之荃.RING-OPENING POLYMERIZATION OFε-CAPROLACTONE USING LANTHANIDE TRIS(N-PHENYL-3,5-DI-T-BUTYLSALICYLALDIMINATO)S AS SINGLE COMPONENT CATALYST[J].Chinese Journal of Polymer Science,2007(05):541-544. DOI：

RING-OPENING POLYMERIZATION OFε-CAPROLACTONE USING LANTHANIDE TRIS（N-PHENYL-3,5-DI-T-BUTYLSALICYLALDIMINATO）S AS SINGLE COMPONENT CATALYST[J]. 2007, (5): 541-544. DOI：

摘要

正

Ring-opening polymerization ofε-caprolactone has been carried out by using rare earth Schiff base complexes: lanthanide tris（N-pheny1-3

5-di-t-butylsalicylaldiminato）s[Ln（OPBS）

]as single component catalyst for the first time.The influences of different rare earth elements

monomer and catalyst concentration as well as reaction time on the polymerization were investigated.Mechanism studies showed that monomer inserts into the active site with the acyl-oxygen bond scission rather than the break of alkyl-oxygen bond.

Abstract

Ring-opening polymerization ofε-caprolactone has been carried out by using rare earth Schiff base complexes: lanthanide tris（N-pheny1-3

5-di-t-butylsalicylaldiminato）s[Ln（OPBS）

]as single component catalyst for the first time.The influences of different rare earth elements

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Optically Active Helical Poly(phenyl isocyanide)s Bearing Achiral Benzanilide Pendants: from Controlled Synthesis to Enantioseparation Application

Upgrading Commercially Available Polyethylene to High-value Materials with Strong Mechanical Performance and Hydrophilicity by Blending with Ethylene/meta-Methoxystyrene Copolymers

Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate

Related Author

No data

Related Institution

No data

⁰