SEGMENT DENSITY PROFILES OF COMPACT POLYMER CHAINS CONFINED BETWEEN TWO PARALLEL PLANE WALLS

Your Location：

Home >

Browse articles >

SEGMENT DENSITY PROFILES OF COMPACT POLYMER CHAINS CONFINED BETWEEN TWO PARALLEL PLANE WALLS

Feature Article | Updated：2021-06-21

- SEGMENT DENSITY PROFILES OF COMPACT POLYMER CHAINS CONFINED BETWEEN TWO PARALLEL PLANE WALLS
- Issue 5, Pages: 525-533(2007)
- Affiliations：
  
  1. Department of Physics Wenzhou University Wenzhou 325027
  2. China
- Author bio：
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China（Nos.20274040,20574052）();the Program for New Century Excellent Talents in Universities（No.NCET-05-0538）();the Natural Science Foundation of Zhejiang Province（Nos.R404047,Y405011,Y405553）();China Postdoctoral Science Foundation（No.20060401064）.()
- DOI：
  CLC： O631.3
- Published：2007
- Accepted：
Scan QR Code
[1]章林溪.SEGMENT DENSITY PROFILES OF COMPACT POLYMER CHAINS CONFINED BETWEEN TWO PARALLEL PLANE WALLS[J].Chinese Journal of Polymer Science,2007(05):525-533.

SEGMENT DENSITY PROFILES OF COMPACT POLYMER CHAINS CONFINED BETWEEN TWO PARALLEL PLANE WALLS[J]. 2007, (5): 525-533.
[1]章林溪.SEGMENT DENSITY PROFILES OF COMPACT POLYMER CHAINS CONFINED BETWEEN TWO PARALLEL PLANE WALLS[J].Chinese Journal of Polymer Science,2007(05):525-533. DOI：

SEGMENT DENSITY PROFILES OF COMPACT POLYMER CHAINS CONFINED BETWEEN TWO PARALLEL PLANE WALLS[J]. 2007, (5): 525-533. DOI：

摘要

正

We use the pruned-enriched Rosenbluth method to investigate systematically the segment density profiles of compact polymer chains confined between two parallel plane walls.The non-adsorption case of adsorption interaction energyε=0 and the weak adsorption case ofε=-1 are considered for the compact polymer chains with different chain lengths N and different separation distances between two walls D.Several special entropy effects on the confined compact polymer chains

such as a damped oscillation in the segment density profile for the large separation distance D

are observed and discussed for different separation distances D in the non-adsorption case.In the weak adsorption case

investigations on the segment density profiles indicate that the competition between the entropy and adsorption effects results in an obvious depletion layer.Moreover

the scaling laws of the damped oscillation period T

and the depletion layer width L

are obtained for the confined compact chains.Most of these results are obtained for the first time so far as we know

which are expected to understand the properties of the confined compact polymer chains more completely.

Abstract

such as a damped oscillation in the segment density profile for the large separation distance D

are observed and discussed for different separation distances D in the non-adsorption case.In the weak adsorption case

investigations on the segment density profiles indicate that the competition between the entropy and adsorption effects results in an obvious depletion layer.Moreover

the scaling laws of the damped oscillation period T

and the depletion layer width L

are obtained for the confined compact chains.Most of these results are obtained for the first time so far as we know

which are expected to understand the properties of the confined compact polymer chains more completely.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

On-demand Peelable UV-curable Adhesives with Superior Bonding Strength: Rational Molecular Engineering of Cohesion-adhesion Synergy

Multiple-Responsive Chiral Hydrogels from Helical Dendronized Poly(phenylacetylene)s

Bioinspired Zinc-doped Nano Hydroxyapatite Reinforced Poly(lactic acid) Composites for Bone Repair

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid

Molecularly Engineered Polyimide Films with Switchable Cavitation for Bidirectional Passive Thermal Regulation

Related Author

No data

Related Institution

No data

⁰