PYRIDINATION OF POLY（VINYL CHLORIDE） via A HOMOLYTIC PATHWAY

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PYRIDINATION OF POLY（VINYL CHLORIDE） via A HOMOLYTIC PATHWAY

Papers | Updated：2021-06-21

- PYRIDINATION OF POLY（VINYL CHLORIDE） via A HOMOLYTIC PATHWAY
- Issue 3, Pages: 297-302(2007)
- Affiliations：
  
  1.   Laboratoire de Chimie-Physique Moléculaire et Macromoléculaire Faculté des Sciences de l’Ingénieur Département de Chimie Industrielle
  2.   Université Sad Dahlab de Blida
  3.   Route de Souma
  4.   B. P. 270
  5.   Blida 09000
  6.   Algeria
- Author bio：
- Funds：
- DOI：
  CLC： TQ325.3
- Published：2007
- Accepted：
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[1]Sad Moulay,Zakia Zeffouni.PYRIDINATION OF POLY(VINYL CHLORIDE) via A HOMOLYTIC PATHWAY[J].Chinese Journal of Polymer Science,2007(03):297-302.

PYRIDINATION OF POLY（VINYL CHLORIDE） via A HOMOLYTIC PATHWAY[J]. 2007, (3): 297-302.
[1]Sad Moulay,Zakia Zeffouni.PYRIDINATION OF POLY(VINYL CHLORIDE) via A HOMOLYTIC PATHWAY[J].Chinese Journal of Polymer Science,2007(03):297-302. DOI：

PYRIDINATION OF POLY（VINYL CHLORIDE） via A HOMOLYTIC PATHWAY[J]. 2007, (3): 297-302. DOI：

摘要

<正>PVC was subjected to a chemical modification aiming at replacing the chlorine atoms by pyridine groups via a homolytic route. Pyridine groups were peculiarly affixed to the PVC matrix via a carbon-carbon bond rather than a carbon-nitrogen one. PVC was first iodinated using the Conant-Finkelstein reaction

followed by the application of the homolytic conditions of Minisci to generate pyridinated PVC with a varying degree of substitution. The extent of substitution was not high; the reaction on 30% iodinated PVC afforded a degree of modification no greater than 3%.

Abstract

PVC was subjected to a chemical modification aiming at replacing the chlorine atoms by pyridine groups via a homolytic route. Pyridine groups were peculiarly affixed to the PVC matrix via a carbon-carbon bond rather than a carbon-nitrogen one. PVC was first iodinated using the Conant-Finkelstein reaction

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