FRACTAL CHARACTER OF PHASE MORPHOLOGY OF HIGH IMPACT POLYSTYRENE/POLY(cis-BUTADIENE) RUBBER BLENDS
|Updated:2021-06-21
|
FRACTAL CHARACTER OF PHASE MORPHOLOGY OF HIGH IMPACT POLYSTYRENE/POLY(cis-BUTADIENE) RUBBER BLENDS
Issue 2, Pages: 125-133(2006)
Affiliations:
1. School of Materials Science & Engineering Tianjin University Tianjin 300072
2. China
Author bio:
Funds:
This work was supported by the National Natural Science Foundation of China (No. 50390090).()
DOI:
CLC:TQ330.1
Published:2006
Accepted:
Scan QR Code
[1]盛京.FRACTAL CHARACTER OF PHASE MORPHOLOGY OF HIGH IMPACT POLYSTYRENE/POLY(cis-BUTADIENE) RUBBER BLENDS[J].Chinese Journal of Polymer Science,2006(02):125-133.
FRACTAL CHARACTER OF PHASE MORPHOLOGY OF HIGH IMPACT POLYSTYRENE/POLY(cis-BUTADIENE) RUBBER BLENDS[J]. 2006, (2): 125-133.
[1]盛京.FRACTAL CHARACTER OF PHASE MORPHOLOGY OF HIGH IMPACT POLYSTYRENE/POLY(cis-BUTADIENE) RUBBER BLENDS[J].Chinese Journal of Polymer Science,2006(02):125-133.DOI:
FRACTAL CHARACTER OF PHASE MORPHOLOGY OF HIGH IMPACT POLYSTYRENE/POLY(cis-BUTADIENE) RUBBER BLENDS[J]. 2006, (2): 125-133.DOI:
FRACTAL CHARACTER OF PHASE MORPHOLOGY OF HIGH IMPACT POLYSTYRENE/POLY(cis-BUTADIENE) RUBBER BLENDS
<正>Evolution and fractal character of the phase morphology of high impact polystyrene/poly(cis-butadiene) rubber (HIPS/PcBR) blends during melting and mixing were investigated using scanning electron microscopy (SEM). The characteristic length L was defined as the size of particles of the dispersed phase in blends. Different fractal dimensions
Df and Dm
were introduced to study the distribution width of phase dimensions in the dimensionless region and the uniformity of the spatial distribution of particles
respectively. The results showed that the average characteristic length Lm and Df increase as the volume fraction of the dispersed phase increases
when the volume fraction of the dispersed phase is lower than 50%. In other words
the size of particles increases and their distribution in the dimensionless region becomes more uniform. Meanwhile
the uniformity of the spatial distribution becomes more perfect as the volume fraction increases. At a certain composition
Lm decreases in the initial stage of the mixing and levels off in the late stage. In the initial stage
Df becomes large rapidly with the process of blending
which means that the distribution of L in the dimensionless region becomes more uniform. Meanwhile
the spatial distribution tends to be ideal rapidly in the early stage and fluctuates in a definite range in the late stage of the mixing.
Abstract
Evolution and fractal character of the phase morphology of high impact polystyrene/poly(cis-butadiene) rubber (HIPS/PcBR) blends during melting and mixing were investigated using scanning electron microscopy (SEM). The characteristic length L was defined as the size of particles of the dispersed phase in blends. Different fractal dimensions
Df and Dm
were introduced to study the distribution width of phase dimensions in the dimensionless region and the uniformity of the spatial distribution of particles
respectively. The results showed that the average characteristic length Lm and Df increase as the volume fraction of the dispersed phase increases
when the volume fraction of the dispersed phase is lower than 50%. In other words
the size of particles increases and their distribution in the dimensionless region becomes more uniform. Meanwhile
the uniformity of the spatial distribution becomes more perfect as the volume fraction increases. At a certain composition
Lm decreases in the initial stage of the mixing and levels off in the late stage. In the initial stage
Df becomes large rapidly with the process of blending
which means that the distribution of L in the dimensionless region becomes more uniform. Meanwhile
the spatial distribution tends to be ideal rapidly in the early stage and fluctuates in a definite range in the late stage of the mixing.
关键词
Keywords
references
The trial reading is over, you can activate your VIP account to continue reading.