PREPARATION AND MAGNETIC PROPERTIES OF POLYMERIC COMPLEXES CONTAINING 1,10-PHENANTHROLINE

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PREPARATION AND MAGNETIC PROPERTIES OF POLYMERIC COMPLEXES CONTAINING 1,10-PHENANTHROLINE

Updated：2021-06-21

- PREPARATION AND MAGNETIC PROPERTIES OF POLYMERIC COMPLEXES CONTAINING 1,10-PHENANTHROLINE
- Issue 1, Pages: 81-86(2006)
- Affiliations：
- Author bio：
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China（Nos.20374044 and 20434020）.()
- DOI：
  CLC： O631.3
- Published：2006
- Accepted：
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[1].PREPARATION AND MAGNETIC PROPERTIES OF POLYMERIC COMPLEXES CONTAINING 1,10-PHENANTHROLINE[J].Chinese Journal of Polymer Science,2006(01):81-86.

PREPARATION AND MAGNETIC PROPERTIES OF POLYMERIC COMPLEXES CONTAINING 1,10-PHENANTHROLINE[J]. 2006, (1): 81-86.
[1].PREPARATION AND MAGNETIC PROPERTIES OF POLYMERIC COMPLEXES CONTAINING 1,10-PHENANTHROLINE[J].Chinese Journal of Polymer Science,2006(01):81-86. DOI：

PREPARATION AND MAGNETIC PROPERTIES OF POLYMERIC COMPLEXES CONTAINING 1,10-PHENANTHROLINE[J]. 2006, (1): 81-86. DOI：

摘要

正

A series of polymeric complexes were prepared from Fe

or Ni

and poly（Schiff base）（DAPcIPA）

which was obtained by polycondensation of 5

6-diamino-1

10-phenanthroline（DAP）with isophthalaldehyde（IPA）.The structures of the polymer and the polymeric complexes were characterized by IR

H-NMR and elemental analysis.The magnetic behavior of these complexes was measured as a function of magnetic field strength（0-3.98×10

A/m）at 5 K and as a function of temperature（5-300 K）at a magnetic field strength of 2.39×10

A/m.Experimental results show that DAPcIPA-Ni

DAPcIPA-Co

are soft ferromagnets while DAPcIPA-Fe

exhibits features of an antiferromagnet.

Abstract

A series of polymeric complexes were prepared from Fe

or Ni

and poly（Schiff base）（DAPcIPA）

which was obtained by polycondensation of 5

6-diamino-1

10-phenanthroline（DAP）with isophthalaldehyde（IPA）.The structures of the polymer and the polymeric complexes were characterized by IR

H-NMR and elemental analysis.The magnetic behavior of these complexes was measured as a function of magnetic field strength（0-3.98×10

A/m）at 5 K and as a function of temperature（5-300 K）at a magnetic field strength of 2.39×10

A/m.Experimental results show that DAPcIPA-Ni

DAPcIPA-Co

are soft ferromagnets while DAPcIPA-Fe

exhibits features of an antiferromagnet.

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