STRUCTURE EVOLUTION OF POLYMER CHAINS FOR NECKING FORMATION IN HIGH-SPEED FIBER SPINNING PROCESS
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STRUCTURE EVOLUTION OF POLYMER CHAINS FOR NECKING FORMATION IN HIGH-SPEED FIBER SPINNING PROCESS
Issue 1, Pages: 1-11(2006)
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This work was financially supported by the National Natural Science Foundation of China(Nos.20204007,50390090,20490220,10590355)the Doctoral Foundation of National Education Committee of China(No.20030248008)the 863 Project of China(No.2002AA336120).()
DOI:
CLC:O631.3
Published:2006
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[1].STRUCTURE EVOLUTION OF POLYMER CHAINS FOR NECKING FORMATION IN HIGH-SPEED FIBER SPINNING PROCESS[J].Chinese Journal of Polymer Science,2006(01):1-11.
STRUCTURE EVOLUTION OF POLYMER CHAINS FOR NECKING FORMATION IN HIGH-SPEED FIBER SPINNING PROCESS[J]. 2006, (1): 1-11.
[1].STRUCTURE EVOLUTION OF POLYMER CHAINS FOR NECKING FORMATION IN HIGH-SPEED FIBER SPINNING PROCESS[J].Chinese Journal of Polymer Science,2006(01):1-11.DOI:
STRUCTURE EVOLUTION OF POLYMER CHAINS FOR NECKING FORMATION IN HIGH-SPEED FIBER SPINNING PROCESS[J]. 2006, (1): 1-11.DOI:
STRUCTURE EVOLUTION OF POLYMER CHAINS FOR NECKING FORMATION IN HIGH-SPEED FIBER SPINNING PROCESS
<正>Finite element method is used to simulate the high-speed melt spinning process
based on the equation system proposed by Doufas et al.Calculation predicts a neck-like deformation
as well as the related profiles of velocity
diameter
temperature
chain orientation
and crystallinity in the fiber spinning process.Considering combined effects on the process such as flow-induced crystallization
viscoelasticity
filament cooling
air drag
inertia
surface tension and gravity
the simulated material flow behaviors are consistent with those observed for semi-crystalline polymers under various spinning conditions.The structure change of polymer coils in the necking region described by the evolution of conformation tensor is also investigated.Based on the relaxation mechanism of macromolecules in flow field different types of morphology change of polymer chains before and in the neck are proposed
giving a complete prospect of structure evolution and crystallization of semi-crystalline polymer in the high speed fiber spinning process.
Abstract
Finite element method is used to simulate the high-speed melt spinning process
based on the equation system proposed by Doufas et al.Calculation predicts a neck-like deformation
as well as the related profiles of velocity
diameter
temperature
chain orientation
and crystallinity in the fiber spinning process.Considering combined effects on the process such as flow-induced crystallization
viscoelasticity
filament cooling
air drag
inertia
surface tension and gravity
the simulated material flow behaviors are consistent with those observed for semi-crystalline polymers under various spinning conditions.The structure change of polymer coils in the necking region described by the evolution of conformation tensor is also investigated.Based on the relaxation mechanism of macromolecules in flow field different types of morphology change of polymer chains before and in the neck are proposed
giving a complete prospect of structure evolution and crystallization of semi-crystalline polymer in the high speed fiber spinning process.
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