HIGHLY SENSITIVE CATALASE ELECTRODE BASED ON POLYPYRROLE FILMS WITH MICROCONTAINERS
|Updated:2021-06-21
|
HIGHLY SENSITIVE CATALASE ELECTRODE BASED ON POLYPYRROLE FILMS WITH MICROCONTAINERS
Issue 6, Pages: 579-584(2006)
Affiliations:
Author bio:
Funds:
This project was supported by the National Natural Science Foundation of China (Nos. 50533030, 20374034 and 50225311) and 973 projects (No. 2003CB615700).()
DOI:
CLC:X131
Published:2006
Accepted:
Scan QR Code
[1].HIGHLY SENSITIVE CATALASE ELECTRODE BASED ON POLYPYRROLE FILMS WITH MICROCONTAINERS[J].Chinese Journal of Polymer Science,2006(06):579-584.
Yu-ying Gao and Gao-quan Shi Department of Chemistry, Tsinghua University, Beijing 100084, et al. HIGHLY SENSITIVE CATALASE ELECTRODE BASED ON POLYPYRROLE FILMS WITH MICROCONTAINERS[J]. 2006, (6): 579-584.
[1].HIGHLY SENSITIVE CATALASE ELECTRODE BASED ON POLYPYRROLE FILMS WITH MICROCONTAINERS[J].Chinese Journal of Polymer Science,2006(06):579-584.DOI:
Yu-ying Gao and Gao-quan Shi Department of Chemistry, Tsinghua University, Beijing 100084, et al. HIGHLY SENSITIVE CATALASE ELECTRODE BASED ON POLYPYRROLE FILMS WITH MICROCONTAINERS[J]. 2006, (6): 579-584.DOI:
HIGHLY SENSITIVE CATALASE ELECTRODE BASED ON POLYPYRROLE FILMS WITH MICROCONTAINERS
<正>Highly sensitive catalase electrodes for sensing hydrogen peroxide have been fabricated based on polypyrrole films with microcontainers. The microcontainers have a cup-like morphology and are arranged in a density of 4000 units cm-2. Catalase was immobilized into the polypyrrole films with microcontainers (Ppy-mc)
which were coated on a Pt substrate electrode. The catalase/Ppy-mc/Pt electrode showed linear response to hydrogen peroxide in the range of 0-18 mmol/L at a potential of-0.3 V (versus SCE). Its sensitivity was measured to be approximately 3.64μA (mmol/L)-1 cm-2
which is about two times that of the electrode fabricated from a flat Ppy film (catalase/Ppy-flat/Pt electrode). The electrode is highly selective for hydrogen peroxide and its sensitivity is interfered by potential interferents such as ascorbic acid
urea and fructose. Furthermore
such catalase electrodes showed long-term storage stability of 15 days under dry conditions at 4℃.
Abstract
Highly sensitive catalase electrodes for sensing hydrogen peroxide have been fabricated based on polypyrrole films with microcontainers. The microcontainers have a cup-like morphology and are arranged in a density of 4000 units cm-2. Catalase was immobilized into the polypyrrole films with microcontainers (Ppy-mc)
which were coated on a Pt substrate electrode. The catalase/Ppy-mc/Pt electrode showed linear response to hydrogen peroxide in the range of 0-18 mmol/L at a potential of-0.3 V (versus SCE). Its sensitivity was measured to be approximately 3.64μA (mmol/L)-1 cm-2
which is about two times that of the electrode fabricated from a flat Ppy film (catalase/Ppy-flat/Pt electrode). The electrode is highly selective for hydrogen peroxide and its sensitivity is interfered by potential interferents such as ascorbic acid
urea and fructose. Furthermore
such catalase electrodes showed long-term storage stability of 15 days under dry conditions at 4℃.
关键词
Keywords
references
The trial reading is over, you can activate your VIP account to continue reading.