ELECTROCHEMICAL COPOLYMERIZATION OF DIBENZOFURAN AND 3-METHYLTHIOPHENE IN BORON TRIFLUORIDE DIETHYL ETHERATE

Wei-qiang Zhou; Jing-kun Xu; Zhen-hong Wei; Shou-zhi Pu

Your Location：

Home >

Browse articles >

ELECTROCHEMICAL COPOLYMERIZATION OF DIBENZOFURAN AND 3-METHYLTHIOPHENE IN BORON TRIFLUORIDE DIETHYL ETHERATE

Papers | Updated：2021-06-21

- ELECTROCHEMICAL COPOLYMERIZATION OF DIBENZOFURAN AND 3-METHYLTHIOPHENE IN BORON TRIFLUORIDE DIETHYL ETHERATE
- Vol. 26, Issue 1, Pages: 81-90(2008)
- Affiliations：
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 January 2008
- Accepted：
Scan QR Code
Wei-qiang Zhou, Jing-kun Xu, Zhen-hong Wei, et al. ELECTROCHEMICAL COPOLYMERIZATION OF DIBENZOFURAN AND 3-METHYLTHIOPHENE IN BORON TRIFLUORIDE DIETHYL ETHERATE[J]. 2008, 26(1): 81-90.
DOI：

Wei-qiang Zhou, Jing-kun Xu, Zhen-hong Wei, et al. ELECTROCHEMICAL COPOLYMERIZATION OF DIBENZOFURAN AND 3-METHYLTHIOPHENE IN BORON TRIFLUORIDE DIETHYL ETHERATE[J]. 2008, 26(1): 81-90. DOI：

摘要

The copolymerization of dibenzofuran (DBF) and 3-methylthiophene (MeT) was successfully achieved electrochemically by direct anodic oxidation of the monomer mixtures in boron trifluoride diethyl etherate. The effects of applied polymerization potential and the monomer concentration ratios on the copolymerization were investigated by linear sweep voltammetry and cyclic voltammetry (CV). The structure of copolymer films were investigated by UV-Vis

infrared spectroscopy

thermal analysis. As-formed novel copolymers own both the advantages of poly(3-methylthiophene) and poly(dibenzofuran)

that is

good redox activity

good thermal stability. Fluorescence spectra suggested that emission spectrum of copolymer films was blue-shifted in contrast to that of PDBF film.

Abstract

infrared spectroscopy

thermal analysis. As-formed novel copolymers own both the advantages of poly(3-methylthiophene) and poly(dibenzofuran)

that is

good redox activity

good thermal stability. Fluorescence spectra suggested that emission spectrum of copolymer films was blue-shifted in contrast to that of PDBF film.

关键词

Keywords

references

Views

262

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Experimental Investigation of Graphene and TiO2 Reinforced Poly(vinyl alcohol)-based Fiber Metal Laminates

Multiple-Responsive Chiral Hydrogels from Helical Dendronized Poly(phenylacetylene)s

One-handed Helical Poly(m-terphenyl acetylene)s with Broad Optical Activity Range from Ultraviolet-Visible to Near-infrared Regions

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid

Related Author

No data

Related Institution

No data

⁰