SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION

Bo-yong Xue; Kenichi Ogata; Akinori Toyota

Your Location：

Home >

Browse articles >

SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION

Papers | Updated：2021-06-21

- SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION
- Vol. 26, Issue 5, Pages: 525-531(2008)
- Affiliations：
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 September 2008
- Accepted：
Scan QR Code
Bo-yong Xue, Kenichi Ogata, Akinori Toyota. SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION[J]. 2008, 26(5): 525-531.
DOI：

Bo-yong Xue, Kenichi Ogata, Akinori Toyota. SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION[J]. 2008, 26(5): 525-531. DOI：

摘要

Norbornene derivatives exo

endo-2-[2-(3

5-di-tert-butyl-4-hydroxyphenoxy)-acetoxy]methyl-5-norbornene (M1) and 3

5-tetramethyl-4-piperidinyl 5-norbornene-exo

endo-2-carboxylate (M2) were synthesized and polymerized by RuCl2(＝CHPh)(PCy3)2 to prepare a novel kind of bi-functional polymer bearing sterically hindered phenol (SHP) and hindered amine (HLAS) groups via ring-opening metathesis polymerization (ROMP). The resulting copolymers were characterized by gel permeation chromatography (GPC)

1H-NMR and differential scanning calorimetry (DSC). The number average molecular weight (Mn) and functional unit content of the resulting copolymer could be regulated by varying the concentration of catalyst and monomer feed.

Abstract

Norbornene derivatives exo

endo-2-[2-(3

5-di-tert-butyl-4-hydroxyphenoxy)-acetoxy]methyl-5-norbornene (M1) and 3

5-tetramethyl-4-piperidinyl 5-norbornene-exo

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

One-handed Helical Poly(m-terphenyl acetylene)s with Broad Optical Activity Range from Ultraviolet-Visible to Near-infrared Regions

Upgrading Commercially Available Polyethylene to High-value Materials with Strong Mechanical Performance and Hydrophilicity by Blending with Ethylene/meta-Methoxystyrene Copolymers

Highly Regio- and trans-Selective Ring-opening Metathesis Polymerization of Chiral Aza-norbornene with a Simple Phenylimido-Tungsten Catalyst

2026-9 Contents

Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives

Related Author

No data

Related Institution

No data

⁰