SYNTHESIS, CHARACTERIZATION AND CATALYTIC BEHAVIOR OF DIMERIC Co(II) AND Ni(II) COMPLEXES CONTAINIGN N,N'-(PHENYL-2-PYRIDINYLMETHYLENE)-3,3',5,5'-TETRAMETHYLBENZIDINE

Yong Cui; Shu Zhang; Wen-hua Sun

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SYNTHESIS, CHARACTERIZATION AND CATALYTIC BEHAVIOR OF DIMERIC Co(II) AND Ni(II) COMPLEXES CONTAINIGN N,N'-(PHENYL-2-PYRIDINYLMETHYLENE)-3,3',5,5'-TETRAMETHYLBENZIDINE

Papers | Updated：2021-06-21

- SYNTHESIS, CHARACTERIZATION AND CATALYTIC BEHAVIOR OF DIMERIC Co(II) AND Ni(II) COMPLEXES CONTAINIGN N,N'-(PHENYL-2-PYRIDINYLMETHYLENE)-3,3',5,5'-TETRAMETHYLBENZIDINE
- Vol. 26, Issue 5, Pages: 539-545(2008)
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- Published：20 September 2008
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Yong Cui, Shu Zhang, Wen-hua Sun. SYNTHESIS, CHARACTERIZATION AND CATALYTIC BEHAVIOR OF DIMERIC Co(II) AND Ni(II) COMPLEXES CONTAINIGN N,N'-(PHENYL-2-PYRIDINYLMETHYLENE)-3,3',5,5'-TETRAMETHYLBENZIDINE[J]. 2008, 26(5): 539-545.
DOI：

Yong Cui, Shu Zhang, Wen-hua Sun. SYNTHESIS, CHARACTERIZATION AND CATALYTIC BEHAVIOR OF DIMERIC Co(II) AND Ni(II) COMPLEXES CONTAINIGN N,N'-(PHENYL-2-PYRIDINYLMETHYLENE)-3,3',5,5'-TETRAMETHYLBENZIDINE[J]. 2008, 26(5): 539-545. DOI：

摘要

The N

N'-(phenyl-2-pyridinylmethylene)-3

5'-tetramethylbenzidine and its dimeric Co(II) and Ni(II) complexes were synthesized. The organic compound was characterized by elemental analyses

IR and NMR spectra

while the bimetal complexes were determined by elemental analyses

IR spectra as well as the single-crystal X-ray diffraction. The nickel complex showed high activity for ethylene polymerization and its cobalt analogue showed negligible active in ethylene activation.

Abstract

The N

N'-(phenyl-2-pyridinylmethylene)-3

5'-tetramethylbenzidine and its dimeric Co(II) and Ni(II) complexes were synthesized. The organic compound was characterized by elemental analyses

IR and NMR spectra

while the bimetal complexes were determined by elemental analyses

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