VINYL POLYMERIZATION OF NORBORNENE CATALYZED BY [2-(2-BENZIMIDAZOLYL)-6-((1-ARYLIMINOETHYL)PYRIDYL)]NICKEL CHLORIDE/MAO SYSTEM

Qi-song Shi a; b

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VINYL POLYMERIZATION OF NORBORNENE CATALYZED BY [2-(2-BENZIMIDAZOLYL)-6-((1-ARYLIMINOETHYL)PYRIDYL)]NICKEL CHLORIDE/MAO SYSTEM

Papers | Updated：2021-06-21

- VINYL POLYMERIZATION OF NORBORNENE CATALYZED BY [2-(2-BENZIMIDAZOLYL)-6-((1-ARYLIMINOETHYL)PYRIDYL)]NICKEL CHLORIDE/MAO SYSTEM
- Vol. 26, Issue 5, Pages: 561-565(2008)
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- Published：20 September 2008
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Qi-song Shi a, b. VINYL POLYMERIZATION OF NORBORNENE CATALYZED BY [2-(2-BENZIMIDAZOLYL)-6-((1-ARYLIMINOETHYL)PYRIDYL)]NICKEL CHLORIDE/MAO SYSTEM[J]. 2008, 26(5): 561-565.
DOI：

Qi-song Shi a, b. VINYL POLYMERIZATION OF NORBORNENE CATALYZED BY [2-(2-BENZIMIDAZOLYL)-6-((1-ARYLIMINOETHYL)PYRIDYL)]NICKEL CHLORIDE/MAO SYSTEM[J]. 2008, 26(5): 561-565. DOI：

摘要

The catalytic system of [2-(2-benzimidazolyl)-6-((1-aryliminoethyl)pyridyl)]nickel chloride/MAO (methylalu-minoxane) was found to be good active for vinyl polymerization of norbornene and provided polymers with relative narrow molecular distributions. Various reaction parameters

such as the ratios of nickel precursor to MAO or monomer norbornene

and the nature of the ligands in complexes were carefully investigated to realize their effects on the catalytic activities

polymer molecular weight and molecular weight distributions.

Abstract

such as the ratios of nickel precursor to MAO or monomer norbornene

and the nature of the ligands in complexes were carefully investigated to realize their effects on the catalytic activities

polymer molecular weight and molecular weight distributions.

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