PREPARATION OF MICROPOROUS ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE (UHMWPE) BY THERMALLY INDUCED PHASE SEPARATION OF A UHMWPE/LIQUID PARAFFIN MIXTURE

Lie Shen; Mao Peng; Fei Qiao; Jie-lai Zhang

Your Location：

Home >

Browse articles >

PREPARATION OF MICROPOROUS ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE (UHMWPE) BY THERMALLY INDUCED PHASE SEPARATION OF A UHMWPE/LIQUID PARAFFIN MIXTURE

Papers | Updated：2021-06-21

- PREPARATION OF MICROPOROUS ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE (UHMWPE) BY THERMALLY INDUCED PHASE SEPARATION OF A UHMWPE/LIQUID PARAFFIN MIXTURE
- Vol. 26, Issue 6, Pages: 653-657(2008)
- Affiliations：
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 November 2008
- Accepted：
Scan QR Code
Lie Shen, Mao Peng, Fei Qiao, et al. PREPARATION OF MICROPOROUS ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE (UHMWPE) BY THERMALLY INDUCED PHASE SEPARATION OF A UHMWPE/LIQUID PARAFFIN MIXTURE[J]. 2008, 26(6): 653-657.
DOI：

Lie Shen, Mao Peng, Fei Qiao, et al. PREPARATION OF MICROPOROUS ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE (UHMWPE) BY THERMALLY INDUCED PHASE SEPARATION OF A UHMWPE/LIQUID PARAFFIN MIXTURE[J]. 2008, 26(6): 653-657. DOI：

摘要

Ultra-high molecular weight polyethylene (UHMWPE) with a microporous structure was prepared via thermally induced phase separation (TIPS). Liquid paraffin (LP) was used as a diluent in the preparation of microporous UHMWPE. Small angle laser light scattering (SALLS) and differential scanning calorimetry (DSC) were used to determine the phase separation temperatures

i.e. the cloud points and the dynamic crystallization temperatures

respectively. It was found that the cloud points were coincident with the crystallization temperatures

indicating that a solid-liquid phase separation occurred during thermal quenching of the UHMWPE/LP solution

while

no liquid-liquid phase separation above the crystallization temperature was observed. The effects of the content and the molecular weight of UHMWPE on the morphology and average pore size were investigated with field emission scanning electron microscopy (FE-SEM) and mercury porosimetry. With the increase of the content of UHMWPE

the average pore size of the microporous material decreased and the molecular weight of UHMWPE could also influence the pore size slightly.

Abstract

i.e. the cloud points and the dynamic crystallization temperatures

respectively. It was found that the cloud points were coincident with the crystallization temperatures

indicating that a solid-liquid phase separation occurred during thermal quenching of the UHMWPE/LP solution

while

the average pore size of the microporous material decreased and the molecular weight of UHMWPE could also influence the pore size slightly.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Optically Active Helical Poly(phenyl isocyanide)s Bearing Achiral Benzanilide Pendants: from Controlled Synthesis to Enantioseparation Application

Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss

Sliding Dynamics of Ring Chain on a Rod-Coil Block Copolymer in Rotaxane

Experimental Investigation of Graphene and TiO2 Reinforced Poly(vinyl alcohol)-based Fiber Metal Laminates

Related Author

No data

Related Institution

No data

⁰