A new type of aromatic tetraamine containing biphenyl moiety in the side chain was synthesized via a modified Chichibabin’s reaction. 3-Nitro-4-acetamidoacetophenone was reacted with 4-phenyl benzaldehyde in the presence of ammonium acetate to obtain 2

6-bis(3

4-diaminophenyl)-4-biphenyl pyridine (DPPA). A series of polypyrrolones (PPys) were prepared using tetraamine and various aromatic dianhydrides via a two-step cyclization procedure. All the PPys show excellent high temperature stabilities with the initial decomposition temperatures of 530-549℃ and residual weight ratio of 49%-80% at 750℃ in nitrogen. The polymers exhibit no apparent glass transition temperatures (Tgs) except PPy-1 (Tg = 327℃)

which is derived from tetraamine DPPA and 2

2-bis[4-(3

4-dicarboxyphenoxy)-phenyl]propane dianhydride (BPADA). In addition

the polymers have acceptable mechanical properties with the tensile strength of 65-94 MPa. The PPy films show excellent hydrolysis-resistance in alkaline aqueous medium and could maintain most of the properties even after boiling in 10% aqueous sodium hydroxide solution for a week.