NiCl2(bpy) catalyzed polycondensation between p-dibromobenzene and m-dibromobenzene has been carried outunder vdrious conditions. The polycondensation endows the copolymer with an Mn of 2300 (by GPC
polystyrene standards)and good solubility in organic solvents. The fluorescence spectra of the copolymer measured with tetrahydrofuran solutionshows an emission maximum (λmax) at 372.8 nm
whereas for the film the maximum shifts to 436.6 nm.
Abstract
NiCl2(bpy) catalyzed polycondensation between p-dibromobenzene and m-dibromobenzene has been carried outunder vdrious conditions. The polycondensation endows the copolymer with an Mn of 2300 (by GPC
polystyrene standards)and good solubility in organic solvents. The fluorescence spectra of the copolymer measured with tetrahydrofuran solutionshows an emission maximum (λmax) at 372.8 nm
whereas for the film the maximum shifts to 436.6 nm.
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