The one plus one (1 + 1) mode of hydrosilation reaction of ladderlike cis-isotatic polyallylsilsesquioxane (Allyl-T)and polyhydrosilsesquioxane (H-T) using dicyclopentadienylplatinumdichloride (Cp2PtCl2) as the catalyst leads to theformation of a new polyorganosiloxane (POS). The presence of nanoscale tubular structure in the product POS waspreliminarily proved by IR
1H-NMR
differential scanning calorimetry (DSC)
X-ray diffraction (XRD)
gel permeation chromatography (GPC)
atomic force microscopy(AFM)and molecular simulation.
Abstract
The one plus one (1 + 1) mode of hydrosilation reaction of ladderlike cis-isotatic polyallylsilsesquioxane (Allyl-T)and polyhydrosilsesquioxane (H-T) using dicyclopentadienylplatinumdichloride (Cp2PtCl2) as the catalyst leads to theformation of a new polyorganosiloxane (POS). The presence of nanoscale tubular structure in the product POS waspreliminarily proved by IR
1H-NMR
differential scanning calorimetry (DSC)
X-ray diffraction (XRD)
gel permeation chromatography (GPC)
atomic force microscopy(AFM)and molecular simulation.
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