CURING KINETICS AND PROPERTIES OF ACRYLIC RESIN CURED WITH AZIRIDINE CROSSLINKER

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CURING KINETICS AND PROPERTIES OF ACRYLIC RESIN CURED WITH AZIRIDINE CROSSLINKER

Papers | Updated：2021-06-21

- CURING KINETICS AND PROPERTIES OF ACRYLIC RESIN CURED WITH AZIRIDINE CROSSLINKER
- Vol. 20, Issue 1, Pages: 65-70(2002)
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- Published：20 February 2002
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CURING KINETICS AND PROPERTIES OF ACRYLIC RESIN CURED WITH AZIRIDINE CROSSLINKER[J]. 2002, 20(1): 65-70.
DOI：

CURING KINETICS AND PROPERTIES OF ACRYLIC RESIN CURED WITH AZIRIDINE CROSSLINKER[J]. 2002, 20(1): 65-70. DOI：

摘要

A kind of aziridine crosslinkers was synthesized and used to crosslink acrylate copolymers. The crosslinkingproperties and curing kinetics of the resin were studied. It was found that with the increase of the content of crosslinker in theemulsion

the mechanical properties and solvent resistance of the resin will be apparently improved

but its glass transitiontemperature (Tg) is very low. The lowest amount of crosslinker used in the acrylic resin emulsion is 0.25%. Curing kinetics studied by DSC show that this curing reaction occurs readily because the apparent activation energy of the reaction is low (65.1kJ/mol).These results demonstrate that the aziridine crosslinker is indeed a low temperature crosslinking agent and can be used at room temperature.

Abstract

the mechanical properties and solvent resistance of the resin will be apparently improved

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