ENHANCEMENT OF DAMPING PERFORMANCE OF POLYMERS BY FUNCTIONAL SMALL MOLECULES

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ENHANCEMENT OF DAMPING PERFORMANCE OF POLYMERS BY FUNCTIONAL SMALL MOLECULES

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- ENHANCEMENT OF DAMPING PERFORMANCE OF POLYMERS BY FUNCTIONAL SMALL MOLECULES
- Vol. 20, Issue 2, Pages: 119-127(2002)
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- Published：20 April 2002
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ENHANCEMENT OF DAMPING PERFORMANCE OF POLYMERS BY FUNCTIONAL SMALL MOLECULES[J]. 2002, 20(2): 119-127.
DOI：

ENHANCEMENT OF DAMPING PERFORMANCE OF POLYMERS BY FUNCTIONAL SMALL MOLECULES[J]. 2002, 20(2): 119-127. DOI：

摘要

The addition effects of organic small molecular substances N

N'-dicyclohexyl-benzothiazyl-2-sulfenamide(DZ)and 3

9-bis{1

1-dimethyl-2[β-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionyloxy]ethyl}-2

10-tetraoxaspiro [5

5]-un-decane (AO-80) on the dynamic mechanical properties of chlorinated polyethylene (CPE)

chlorinated polypropylene (CPP)

acrylate rubber (ACM) and their blends were investigated. In the case of compatible systems such as CPE/DZ and ACM/AO-80

the height of the loss tangent(tanδ)peak of a matrix polymer (CPE or ACM) increases

and its peak position shifts to a higher temperature with the addition of DZ or AO-80.By contrast

for incompatible CPE/AO-80

a novel transition appeared above the glass transition temperature of CPE.This additional transition was assigned to dissociation of the intermolecular hydrogen bond between the α-hydrogen of CPE and the hydroxyl groups of AO-80 within the AO-80-rich domain.This will provide a new concept for developing damping material.However

the minimum value between two tan δ peaks is lower.It was found that the temperature dependence of tan δcould be improved by adding chlorinated paraffin (CP) or ACM to CPE/AO-80.In addition

another termary system of ACM/CPP with more AO-80 was found to be a very good self-adhesive damping material because of the appearance of a novel transition due to an interfacial layer of ACM/CPP.

Abstract

The addition effects of organic small molecular substances N

N'-dicyclohexyl-benzothiazyl-2-sulfenamide(DZ)and 3

9-bis{1

1-dimethyl-2[β-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionyloxy]ethyl}-2

10-tetraoxaspiro [5

5]-un-decane (AO-80) on the dynamic mechanical properties of chlorinated polyethylene (CPE)

chlorinated polypropylene (CPP)

acrylate rubber (ACM) and their blends were investigated. In the case of compatible systems such as CPE/DZ and ACM/AO-80

the height of the loss tangent(tanδ)peak of a matrix polymer (CPE or ACM) increases

and its peak position shifts to a higher temperature with the addition of DZ or AO-80.By contrast

for incompatible CPE/AO-80

the minimum value between two tan δ peaks is lower.It was found that the temperature dependence of tan δcould be improved by adding chlorinated paraffin (CP) or ACM to CPE/AO-80.In addition

another termary system of ACM/CPP with more AO-80 was found to be a very good self-adhesive damping material because of the appearance of a novel transition due to an interfacial layer of ACM/CPP.

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