COPOLYMERIZATION AND DETERMINATION OF MONOMER REACTIVITY RATIOS OF DL-LACTIDE WITH 3-BENZYLOXYMETHYL-1,4-DIOXANE-2,5-DIONE*

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COPOLYMERIZATION AND DETERMINATION OF MONOMER REACTIVITY RATIOS OF DL-LACTIDE WITH 3-BENZYLOXYMETHYL-1,4-DIOXANE-2,5-DIONE*

Papers | Updated：2021-06-21

- COPOLYMERIZATION AND DETERMINATION OF MONOMER REACTIVITY RATIOS OF DL-LACTIDE WITH 3-BENZYLOXYMETHYL-1,4-DIOXANE-2,5-DIONE*
- Vol. 20, Issue 5, Pages: 413-417(2002)
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- Published：20 October 2002
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COPOLYMERIZATION AND DETERMINATION OF MONOMER REACTIVITY RATIOS OF DL-LACTIDE WITH 3-BENZYLOXYMETHYL-1,4-DIOXANE-2,5-DIONE*[J]. 2002, 20(5): 413-417.
DOI：

COPOLYMERIZATION AND DETERMINATION OF MONOMER REACTIVITY RATIOS OF DL-LACTIDE WITH 3-BENZYLOXYMETHYL-1,4-DIOXANE-2,5-DIONE*[J]. 2002, 20(5): 413-417. DOI：

摘要

The copolymerization of DL-LA and 3-BMG was carried out in bulk with Stannous 2-ethylhexanoate as thecatalyst. A series of copolymers with pendant protected groups were obtained and characterized by 1H-NMR and GPCanalysis. The monomer reactivity ratios were evaluated by the Fineman-Ross method and the Kelen-Tudos method and foundto be rBMG = 1.96 and rLA = 0.37

respectively.

Abstract

respectively.

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