SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*

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SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*

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- SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*
- Vol. 20, Issue 2, Pages: 177-180(2002)
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- Published：20 April 2002
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SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*[J]. 2002, 20(2): 177-180.
DOI：

SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*[J]. 2002, 20(2): 177-180. DOI：

摘要

A route was proposed to synthesize 3-benryl-glyceric acid (3-BGA) as an important intermediate for the synthesis ofa novel six-membered cyclic ester monomer - 3-benzyloxymethyl-1

4-dioxane-2

5-dione (3-BMG). According to this route

3-BGA was obtained from ring-opening reaction of benzyl alcohol with methyl glycidate

which was prepared from theepoxidation of methyl acrylate using sodium hypochlorite as the oxidant.

Abstract

A route was proposed to synthesize 3-benryl-glyceric acid (3-BGA) as an important intermediate for the synthesis ofa novel six-membered cyclic ester monomer - 3-benzyloxymethyl-1

4-dioxane-2

5-dione (3-BMG). According to this route

3-BGA was obtained from ring-opening reaction of benzyl alcohol with methyl glycidate

which was prepared from theepoxidation of methyl acrylate using sodium hypochlorite as the oxidant.

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