Hyperbranched aromatic polpmers were prepared by Friedel-Crafts reaction with Lewis acid
AlCl3 and ZnCl3
asthe catalysts. In this work
hyperbranched polybenzyl (PB) and poly(methylene) naphthalene(PN) were synthesized andcharacterized by 1H-NMR and GPc. In addition
their florescence properties were measured with steady-state florescencespectra in THF and ethylene dichloride. The quantum yields of polybenzyl and poly(methylene)naphthalene in ethylenedichloride are much larger than those in THF.
Abstract
Hyperbranched aromatic polpmers were prepared by Friedel-Crafts reaction with Lewis acid
AlCl3 and ZnCl3
asthe catalysts. In this work
hyperbranched polybenzyl (PB) and poly(methylene) naphthalene(PN) were synthesized andcharacterized by 1H-NMR and GPc. In addition
their florescence properties were measured with steady-state florescencespectra in THF and ethylene dichloride. The quantum yields of polybenzyl and poly(methylene)naphthalene in ethylenedichloride are much larger than those in THF.
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