SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*

Your Location：

Home >

Browse articles >

SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*

Papers | Updated：2021-06-21

- SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*
- Vol. 19, Issue 1, Pages: 1-6(2001)
- Affiliations：
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 February 2001
- Accepted：
Scan QR Code
SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*[J]. 2001, 19(1): 1-6.
DOI：

SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*[J]. 2001, 19(1): 1-6. DOI：

摘要

A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer

3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS)

was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp2PtC12) catalyst in high yield. The synthesized polynitroorganosiloxane

which has potential application as a precursor for synthesizing advanced functional polymers

was characterized by FTIR

1H-NMR

13C-NMR

29Si-NMR

vapor pressure osmometry (VPO) and gel permeation chromatography (GPC).

Abstract

A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer

3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS)

was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp2PtC12) catalyst in high yield. The synthesized polynitroorganosiloxane

which has potential application as a precursor for synthesizing advanced functional polymers

was characterized by FTIR

1H-NMR

13C-NMR

29Si-NMR

vapor pressure osmometry (VPO) and gel permeation chromatography (GPC).

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate

Optically Active Helical Poly(phenyl isocyanide)s Bearing Achiral Benzanilide Pendants: from Controlled Synthesis to Enantioseparation Application

Enhanced Segment Mobility Promotes Stereocomplex Crystallization in Polymer Blends via Elevated Segmental Miscibility

Related Author

No data

Related Institution

No data

⁰