REVERSE ATOM TRANSFER RADICAL POLYMERIZATION OF STYRENE WITH COPPER-BASED CATALYST

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REVERSE ATOM TRANSFER RADICAL POLYMERIZATION OF STYRENE WITH COPPER-BASED CATALYST

Papers | Updated：2021-06-21

- REVERSE ATOM TRANSFER RADICAL POLYMERIZATION OF STYRENE WITH COPPER-BASED CATALYST
- Vol. 19, Issue 1, Pages: 59-64(2001)
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- Published：20 February 2001
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REVERSE ATOM TRANSFER RADICAL POLYMERIZATION OF STYRENE WITH COPPER-BASED CATALYST[J]. 2001, 19(1): 59-64.
DOI：

REVERSE ATOM TRANSFER RADICAL POLYMERIZATION OF STYRENE WITH COPPER-BASED CATALYST[J]. 2001, 19(1): 59-64. DOI：

摘要

"Living"/controlled radical polymerization of styrene was carried out with diethyl 2

3-dicyano-2

3-diphenylsuccinate (DCDPS)/CuCl2/bipyridine (bipy) initiation system at 120℃. The molecular weights of resultant PSt increased with the monomer conversion and the polydispersities were in the range of 1.37 ～ 1.52. A linear ln([M]o/[M])versus time plot was also obtained indicating the constant concentration of growing radicals during the polymerization with this initiation system. End group analysis by 1H-NMR spectroscopic studies showed that the end groups of the polymer obtained is cω-functionalized by a chlorine group from the catalyst and a-functionalized by a (carbethoxy-cyano-phenyl)methyl group from the fragments of the initiator. Having C1 atom at the chain end

the PSt obtained can be used as a macroinitiator to promote a chain-extension reaction with fresh St and block copolymerization reaction with a second monomer

such as methyl methacrylate

in the presence of CuC1/bipy catalyst via a conventional ATRP process.

Abstract

"Living"/controlled radical polymerization of styrene was carried out with diethyl 2

3-dicyano-2

the PSt obtained can be used as a macroinitiator to promote a chain-extension reaction with fresh St and block copolymerization reaction with a second monomer

such as methyl methacrylate

in the presence of CuC1/bipy catalyst via a conventional ATRP process.

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