MOLECULAR DESIGN OF FUNCTIONAL POLYMERS BASED ON UNIQUE PROPERTIES OF POLYMER CHAINS

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MOLECULAR DESIGN OF FUNCTIONAL POLYMERS BASED ON UNIQUE PROPERTIES OF POLYMER CHAINS

Papers | Updated：2021-06-21

- MOLECULAR DESIGN OF FUNCTIONAL POLYMERS BASED ON UNIQUE PROPERTIES OF POLYMER CHAINS
- Vol. 18, Issue 3, Pages: 209-226(2000)
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- Published：20 June 2000
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MOLECULAR DESIGN OF FUNCTIONAL POLYMERS BASED ON UNIQUE PROPERTIES OF POLYMER CHAINS[J]. 2000, 18(3): 209-226.
DOI：

MOLECULAR DESIGN OF FUNCTIONAL POLYMERS BASED ON UNIQUE PROPERTIES OF POLYMER CHAINS[J]. 2000, 18(3): 209-226. DOI：

摘要

The inclusion complex formation of -CD

-CD

and -CD with various water-soluble polymers has beeninvestigated

and the relationship between the chain cross-sectional areas of the polymers and the diameters of the cavities ofcyclodextrins (molecular recognition) was found. Polyrotaxanes and tubular polymers were prepared on the basis ofmolecular recognition. Several kinds of polymers having tetraphenylporphyrin (TPP) and paramagnetic metallotetraphenyl-prophyrin (AgTTP

CuTPP

VOTPP or ZnTPP) have been prepared by radical polymerization of the corresponding monomers.Visible spectra of these polymers show hypochromism in the Soret bands of TPP moieties as compared with those of monomers.Polymer effects were observed in the magnetic behavior and oxygen adsorption of paramagnetic metallotetraphenylporphyrin moieties.Moreover

polymer effects on photophysical and photophysical and photochemical behavior were found in the amphiphilic polymers covalently tethered with small amounts of zinc(II)-tetraphenylporphyrin(ZnTPP).

Abstract

The inclusion complex formation of -CD

-CD

and -CD with various water-soluble polymers has beeninvestigated

CuTPP

polymer effects on photophysical and photophysical and photochemical behavior were found in the amphiphilic polymers covalently tethered with small amounts of zinc(II)-tetraphenylporphyrin(ZnTPP).

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Special Topic: Chirality in Polymers

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