PERFORMANCE AND INITIATION MECHANISM OF ISOPROPYLTHIOXANTHONE IN SURFACE PHOTOGRAFTING

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PERFORMANCE AND INITIATION MECHANISM OF ISOPROPYLTHIOXANTHONE IN SURFACE PHOTOGRAFTING

Papers | Updated：2021-06-21

- PERFORMANCE AND INITIATION MECHANISM OF ISOPROPYLTHIOXANTHONE IN SURFACE PHOTOGRAFTING
- Vol. 18, Issue 5, Pages: 431-435(2000)
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- Published：20 October 2000
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PERFORMANCE AND INITIATION MECHANISM OF ISOPROPYLTHIOXANTHONE IN SURFACE PHOTOGRAFTING[J]. 2000, 18(5): 431-435.
DOI：

PERFORMANCE AND INITIATION MECHANISM OF ISOPROPYLTHIOXANTHONE IN SURFACE PHOTOGRAFTING[J]. 2000, 18(5): 431-435. DOI：

摘要

In a polymerization model with low density polyethylene (LDPE) as the substrate and acrylic acid (AA) as themonomer

the performance of isopropylthioxanthone (ITX) in initiating surface photografting polymerization was evaluated.The results show that the reactivity of photopolymerization and photografting of ITX locate between benzophenone (BP) andbenzildimethylketal (BDK) for polymerization

BDK> ITX> BP; for surface grafting polymerization

BP> ITX>BDK.These results can be explained by a reaction mechanism of the inter-molecular or intra-molecular hydrogen abstraction reaction of ITX.

Abstract

In a polymerization model with low density polyethylene (LDPE) as the substrate and acrylic acid (AA) as themonomer

BDK> ITX> BP; for surface grafting polymerization

BP> ITX>BDK.These results can be explained by a reaction mechanism of the inter-molecular or intra-molecular hydrogen abstraction reaction of ITX.

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