A DSC STUDY OF PHOTOPOLYMERIZATION OF POLYESTERS CONTAINING CONJUGATED DIACETYLENES

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A DSC STUDY OF PHOTOPOLYMERIZATION OF POLYESTERS CONTAINING CONJUGATED DIACETYLENES

Papers | Updated：2021-06-21

- A DSC STUDY OF PHOTOPOLYMERIZATION OF POLYESTERS CONTAINING CONJUGATED DIACETYLENES
- Vol. 18, Issue 4, Pages: 351-356(2000)
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- Published：20 August 2000
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A DSC STUDY OF PHOTOPOLYMERIZATION OF POLYESTERS CONTAINING CONJUGATED DIACETYLENES[J]. 2000, 18(4): 351-356.
DOI：

A DSC STUDY OF PHOTOPOLYMERIZATION OF POLYESTERS CONTAINING CONJUGATED DIACETYLENES[J]. 2000, 18(4): 351-356. DOI：

摘要

The photopolymerization of two kinds of prepolyesters containing conjugated diacetylene (PDA-6 and PDA-12)was investigated using DSC. By measuring the endothermic enthalpy of the prepolymers after different UV-irradiation times

the polymerizations were found to follow the first-order rate law which agreed with the results of other investigators using adifferent method. The endothermic enthalpy measurements of PDA-6 and PDA-12 before UV-irradiation precluded the possibility that the decrease of endothermic enthalpy was caused by thermal polymerization.

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