MQ silicone resins were prepared through hydrolytic condensation of ethyl polysilicate ortetraethoxysilane and hexamethyl disiloxane. The unit ratio of the MQ resins was determined by 29Si-NMR.The relationship of the unit ratio of the product resins with that in the feed was studied. When the reactionwas catalyzed by aqueous hydrochloric acid
and the unit ratio of M to Q in the feed was more than 1
the unitratio of the product was usually lower than that of the feed. The MQ silicon with an unit ratio of M/Q>2 could not be obtained.However if the reaction was catalyzed by concentrated sulfuric acid and the reverse hydrolysis process was employed
MQ silicone resin with very high M/Q ratio was successfully prepared.
Abstract
MQ silicone resins were prepared through hydrolytic condensation of ethyl polysilicate ortetraethoxysilane and hexamethyl disiloxane. The unit ratio of the MQ resins was determined by 29Si-NMR.The relationship of the unit ratio of the product resins with that in the feed was studied. When the reactionwas catalyzed by aqueous hydrochloric acid
and the unit ratio of M to Q in the feed was more than 1
the unitratio of the product was usually lower than that of the feed. The MQ silicon with an unit ratio of M/Q>2 could not be obtained.However if the reaction was catalyzed by concentrated sulfuric acid and the reverse hydrolysis process was employed
MQ silicone resin with very high M/Q ratio was successfully prepared.
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