STABILITY OF EMULSIFIER-FREE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE/BUTYL ACRYLATE/SODIUM MONO(ETHYL POLYOXYETHYLENE)MALEATE

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STABILITY OF EMULSIFIER-FREE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE/BUTYL ACRYLATE/SODIUM MONO(ETHYL POLYOXYETHYLENE)MALEATE

Papers | Updated：2021-06-21

- STABILITY OF EMULSIFIER-FREE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE/BUTYL ACRYLATE/SODIUM MONO(ETHYL POLYOXYETHYLENE)MALEATE
- Vol. 17, Issue 6, Pages: 571-577(1999)
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- Published：20 December 1999
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STABILITY OF EMULSIFIER-FREE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE/BUTYL ACRYLATE/SODIUM MONO(ETHYL POLYOXYETHYLENE)MALEATE[J]. 1999, 17(6): 571-577.
DOI：

STABILITY OF EMULSIFIER-FREE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE/BUTYL ACRYLATE/SODIUM MONO(ETHYL POLYOXYETHYLENE)MALEATE[J]. 1999, 17(6): 571-577. DOI：

摘要

A series of new water-soluble bifunctional comonomers having both carboxyl and alkylpolyoxyethylene groups

such as sodium mono(ethyl polyoxyethylene) maleate (ZE series) with variousmolecular weights of polyoxyethylene ethyl ether

were synthesized and characterized. The effects of thestructural factor

the amount and feeding mode of the comonomers

the initiator concentration andpolymerization temperature on the stability of emulsifier-free emulsion copolymerization of methylmethacrylate (MMA) and butyl acrylate(BA) in the presence of a small amount of ZE with potassium persulfate as initiator were investigated.Stable almost monodispersed MMA/BA/ZE emulsifier-free latex particles were prepared.

Abstract

A series of new water-soluble bifunctional comonomers having both carboxyl and alkylpolyoxyethylene groups

such as sodium mono(ethyl polyoxyethylene) maleate (ZE series) with variousmolecular weights of polyoxyethylene ethyl ether

were synthesized and characterized. The effects of thestructural factor

the amount and feeding mode of the comonomers

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