PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*

ZHAO Chunying; YANG Yongyuan; LI Lidong; XU Wei; FENG Shujing

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PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*

Papers | Updated：2021-06-21

- PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*
- Vol. 16, Issue 4, Pages: 310-315(1998)
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- Published：20 December 1998
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ZHAO Chunying, YANG Yongyuan, LI Lidong, et al. PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*[J]. 1998, 16(4): 310-315.
DOI：

ZHAO Chunying, YANG Yongyuan, LI Lidong, et al. PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*[J]. 1998, 16(4): 310-315. DOI：

摘要

The photoinitiating system composed of 1-ethyl-3'-methylthiacyanine bro-mide (C-I)

2-chlorohexaarylbiimidazole (o-Cl-HABI) and 3-mercapto-4-methyl-4H-1

4-triazole (MTA)

which act as sensitizer

initiator and hydrogen-donor respectively

can beused to initiate the polymerization of methyl methacrylate (MMA). The kinetic study wascarried out in trichloromathane solution at 30℃ by using dilatometry. The relation be-tween the polymerization rate and the concentrations of C-I

o-Cl-HABI

MTA and MMA was studied.

Abstract

The photoinitiating system composed of 1-ethyl-3'-methylthiacyanine bro-mide (C-I)

2-chlorohexaarylbiimidazole (o-Cl-HABI) and 3-mercapto-4-methyl-4H-1

4-triazole (MTA)

which act as sensitizer

initiator and hydrogen-donor respectively

o-Cl-HABI

MTA and MMA was studied.

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