SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES*
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SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES*
Vol. 16, Issue 3, Pages: 214-218(1998)
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Published:20 September 1998
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ZHAO Weiguo, SHEN Yongjia, LI Yongfang, et al. SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES*[J]. 1998, 16(3): 214-218.
DOI:
ZHAO Weiguo, SHEN Yongjia, LI Yongfang, et al. SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES*[J]. 1998, 16(3): 214-218.DOI:
SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES*
A polymer containing bis(ethylenedithio)-tetrathiafulvalene moiety wassynthesized and its electrochemical properties were studied by cyclic voltammetry. Thecharge transfer complexes of the polymer with TCNQ and I_2 were obtained by chemicaloxidation in dichlorobenzene. All of them are semi-conductors. A film of the polymer wasobtained by casting. Its conductivity
after oxidation with iodine
is 2.24×10~(-6)S·cm~(-1)and its conducting state is stable in air.
Abstract
A polymer containing bis(ethylenedithio)-tetrathiafulvalene moiety wassynthesized and its electrochemical properties were studied by cyclic voltammetry. Thecharge transfer complexes of the polymer with TCNQ and I_2 were obtained by chemicaloxidation in dichlorobenzene. All of them are semi-conductors. A film of the polymer wasobtained by casting. Its conductivity
after oxidation with iodine
is 2.24×10~(-6)S·cm~(-1)and its conducting state is stable in air.
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