A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*

XU Hui; CAO Xinyu; LI Ze; CAO Ming; DAI Daorong; XIE Ping; ZHANG Rongben

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A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*

Papers | Updated：2021-06-21

- A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*
- Vol. 16, Issue 3, Pages: 253-260(1998)
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- Published：20 September 1998
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XU Hui, CAO Xinyu, LI Ze, et al. A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*[J]. 1998, 16(3): 253-260.
DOI：

XU Hui, CAO Xinyu, LI Ze, et al. A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*[J]. 1998, 16(3): 253-260. DOI：

摘要

A novel supramolecular polysiloxane clathrate

POS/C

has been preparedby in-situ encapsulating rodlike p-butoxybenzylidene-p ' - dodecoxyaniline (BBDA )

one kindof Schiff base liquid crystal molecule

within the pore of polyorganosiloxane (POS) whichis prepared by hydrosilylation coupling reaction of polyvinylsilsesquioxane (Vi- T ) withtetramethyldisiloxane (H-MM). Investigation by polarized light microscopy (PLM)

differ-ential scanning calorimetry (DSC)

infrared spectroscopy (IR)

atomic force microscopy (AFM) and molecular simulation gives a preliminary support to the existence of the title supramolecular clathrate.

Abstract

A novel supramolecular polysiloxane clathrate

POS/C

has been preparedby in-situ encapsulating rodlike p-butoxybenzylidene-p ' - dodecoxyaniline (BBDA )

one kindof Schiff base liquid crystal molecule

differ-ential scanning calorimetry (DSC)

infrared spectroscopy (IR)

atomic force microscopy (AFM) and molecular simulation gives a preliminary support to the existence of the title supramolecular clathrate.

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