"LIVING" FREE RADICAL SYNTHESIS OF NOVEL RODCOIL DIBLOCK COPOLYMERS WITH POLYSTYRENE AND MESOGEN-JACKETED LIQUID CRYSTAL POLYMER SEGMENTS*

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- "LIVING" FREE RADICAL SYNTHESIS OF NOVEL RODCOIL DIBLOCK COPOLYMERS WITH POLYSTYRENE AND MESOGEN-JACKETED LIQUID CRYSTAL POLYMER SEGMENTS*
- Vol. 16, Issue 4, Pages: 377-380(1998)
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- Published：20 December 1998
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WAN Xinhua, TU Yingfeng, ZHANG Dong, et al. "LIVING" FREE RADICAL SYNTHESIS OF NOVEL RODCOIL DIBLOCK COPOLYMERS WITH POLYSTYRENE AND MESOGEN-JACKETED LIQUID CRYSTAL POLYMER SEGMENTS*[J]. 1998, 16(4): 377-380.
DOI：

WAN Xinhua, TU Yingfeng, ZHANG Dong, et al. "LIVING" FREE RADICAL SYNTHESIS OF NOVEL RODCOIL DIBLOCK COPOLYMERS WITH POLYSTYRENE AND MESOGEN-JACKETED LIQUID CRYSTAL POLYMER SEGMENTS*[J]. 1998, 16(4): 377-380. DOI：

The synthesis of rod-coil diblock copolymers was achieved for the firsttime by TEMPO-mediated "living" free radical polymerization of styrene and 2

5-bis[(4-methoxyphenyl)oxycarbonyl]styrene(MPCS). The block architecture of the two diblockcopolymers thus prepared

MPCS-b-St(5400/2400) and MPCS-b-St(10800/8700)

was con-firmed by GPC

DSC studies and the formation of multimolecular micelles.

The synthesis of rod-coil diblock copolymers was achieved for the firsttime by TEMPO-mediated "living" free radical polymerization of styrene and 2

5-bis[(4-methoxyphenyl)oxycarbonyl]styrene(MPCS). The block architecture of the two diblockcopolymers thus prepared

MPCS-b-St(5400/2400) and MPCS-b-St(10800/8700)

was con-firmed by GPC

DSC studies and the formation of multimolecular micelles.

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