PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN

WANG Rongmin; HE Yufeng; LEI Ziqiang; WANG Yunpu; LI Shuben

Your Location：

Home >

Browse articles >

PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN

Papers | Updated：2021-06-21

- PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN
- Vol. 16, Issue 1, Pages: 91-96(1998)
- Affiliations：
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 March 1998
- Accepted：
Scan QR Code
WANG Rongmin, HE Yufeng, LEI Ziqiang, et al. PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN[J]. 1998, 16(1): 91-96.
DOI：

WANG Rongmin, HE Yufeng, LEI Ziqiang, et al. PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN[J]. 1998, 16(1): 91-96. DOI：

摘要

The meso- tetraarylporphyrin has been anchored to styrene- divinylbenzenecopolymers by reaction of meso- tetra (4-hydroxylphenyl ) porphyrin with chloromethylatedresin under mild condition. A number of polymer transition metal complexes have beenprepared with the polymer ligand and metal salts. The polymeric ligand and its complexeshave been characterized by electronic spectra

and vibrational spectra. Cyclohexene can behydrogenated with the polymeric porphyrin palladium complex(P-THPPPd) as catalyst

and its catalytic activity was influenced by the polarity of solvents

the contents of water in ethanol or reaction temperature.However

its catalytic activity was lower for intro groups

carbonyl groups and olefins with steric hindrance substityents

and showed no activity for aromatic rings under these conditions.

Abstract

and vibrational spectra. Cyclohexene can behydrogenated with the polymeric porphyrin palladium complex(P-THPPPd) as catalyst

and its catalytic activity was influenced by the polarity of solvents

the contents of water in ethanol or reaction temperature.However

its catalytic activity was lower for intro groups

carbonyl groups and olefins with steric hindrance substityents

and showed no activity for aromatic rings under these conditions.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature

Alternating Poly(ether-alt-ester)s with High Glass Transition Temperature Enabled by Rotationally Constrained Biaryl Units

Special Topic: Chirality in Polymers

Multiple-Responsive Chiral Hydrogels from Helical Dendronized Poly(phenylacetylene)s

Related Author

No data

Related Institution

No data

⁰