POLYMERIZATION MECHANISM OF N-VINYLCARBAZOLE WITH CHIRALLY ORGANIC SALT AS CATALYST

CHEN Chuanfu; SUN Yifei; SU Quan; LIU Weihong; CHEN Yongming; XI Fu

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POLYMERIZATION MECHANISM OF N-VINYLCARBAZOLE WITH CHIRALLY ORGANIC SALT AS CATALYST

Papers | Updated：2021-06-21

- POLYMERIZATION MECHANISM OF N-VINYLCARBAZOLE WITH CHIRALLY ORGANIC SALT AS CATALYST
- Vol. 16, Issue 2, Pages: 126-132(1998)
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- Published：20 June 1998
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CHEN Chuanfu, SUN Yifei, SU Quan, et al. POLYMERIZATION MECHANISM OF N-VINYLCARBAZOLE WITH CHIRALLY ORGANIC SALT AS CATALYST[J]. 1998, 16(2): 126-132.
DOI：

CHEN Chuanfu, SUN Yifei, SU Quan, et al. POLYMERIZATION MECHANISM OF N-VINYLCARBAZOLE WITH CHIRALLY ORGANIC SALT AS CATALYST[J]. 1998, 16(2): 126-132. DOI：

摘要

The polymerization mechanism is described by the conductance changewith the time during the polymerization. The mechanism can be explained by the equi-librium feature (i.e. main ion-pairs) between the free ions and the ion-pairs dissociated bythe organic salt (-) Sp*+ (+) CSA*- (An asterisk represents the chirality) and the schemeof the polymerization process is described mainly by the charge transfer complexes havingchiral induction power.

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