SYNTHESIS AND CHARACTERIZATION OF SOME THERMOTROPIC LIQUID CRYSTALLINE POLYAMIDES*
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SYNTHESIS AND CHARACTERIZATION OF SOME THERMOTROPIC LIQUID CRYSTALLINE POLYAMIDES*
Vol. 15, Issue 4, Pages: 353-361(1997)
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Published:20 December 1997
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ZHOU Deliang, ZHANG Dong, Samuel K.L. TAN, et al. SYNTHESIS AND CHARACTERIZATION OF SOME THERMOTROPIC LIQUID CRYSTALLINE POLYAMIDES*[J]. 1997, 15(4): 353-361.
DOI:
ZHOU Deliang, ZHANG Dong, Samuel K.L. TAN, et al. SYNTHESIS AND CHARACTERIZATION OF SOME THERMOTROPIC LIQUID CRYSTALLINE POLYAMIDES*[J]. 1997, 15(4): 353-361.DOI:
SYNTHESIS AND CHARACTERIZATION OF SOME THERMOTROPIC LIQUID CRYSTALLINE POLYAMIDES*
A series of novel mesogenic polyamides containing a flexible pendent side group wassynthesized by solution condensation polymerization. The new monomers
diacids and di-amines containing flexible elements of diferent lengths
were also synthesized and character-ized by ~1HNMR
mass spectroscopy and elemental analysis. The polymers were character-ized by viscosity measurements
differential scanning calorimetry (DSC)
X-ray diffiactionand polarizing optical microscopy. These studies revealed that polyamides containing flexible elements of a sufficient length exhibited thermotropic liquid crystalline (LC) properties.The melting temperatures of this series of polymers were particularly sensitive to the length of the flexible segment on the main chain and that of the flexible pendent ester side chain.Lyotropic LC behaviours were also observed in solution.
Abstract
A series of novel mesogenic polyamides containing a flexible pendent side group wassynthesized by solution condensation polymerization. The new monomers
diacids and di-amines containing flexible elements of diferent lengths
were also synthesized and character-ized by ~1HNMR
mass spectroscopy and elemental analysis. The polymers were character-ized by viscosity measurements
differential scanning calorimetry (DSC)
X-ray diffiactionand polarizing optical microscopy. These studies revealed that polyamides containing flexible elements of a sufficient length exhibited thermotropic liquid crystalline (LC) properties.The melting temperatures of this series of polymers were particularly sensitive to the length of the flexible segment on the main chain and that of the flexible pendent ester side chain.Lyotropic LC behaviours were also observed in solution.
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