GRAFT POLYMERIZATION OF ACRYLAMIDE ONTO HOMOPOLYMER OF 5-METHYL-5-HEXEN-2, 4-DIONE INITIATED BY CERIC ION*

ZHAO Jingbo; ZHAO Tong; QIU Kunyuan

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GRAFT POLYMERIZATION OF ACRYLAMIDE ONTO HOMOPOLYMER OF 5-METHYL-5-HEXEN-2, 4-DIONE INITIATED BY CERIC ION*

Papers | Updated：2021-06-21

- GRAFT POLYMERIZATION OF ACRYLAMIDE ONTO HOMOPOLYMER OF 5-METHYL-5-HEXEN-2, 4-DIONE INITIATED BY CERIC ION*
- Vol. 15, Issue 1, Pages: 50-56(1997)
- Affiliations：
  
  1.   College of Chemistry and Molecular Engineering
  2.   Peking University
  3.   Beijing 100871
- Author bio：
- Funds：
- DOI：
  CLC： TQ316.6
- Published：20 March 1997
- Accepted：
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[1]赵京波,赵彤,丘坤元.GRAFT POLYMERIZATION OF ACRYLAMIDE ONTO HOMOPOLYMER OF 5-METHYL-5-HEXEN-2, 4-DIONE INITIATED BY CERIC ION[J].Chinese Journal of Polymer Science,1997,{4}(01):50-56.

ZHAO Jingbo, ZHAO Tong, QIU Kunyuan. GRAFT POLYMERIZATION OF ACRYLAMIDE ONTO HOMOPOLYMER OF 5-METHYL-5-HEXEN-2, 4-DIONE INITIATED BY CERIC ION*[J]. 1997, 15(1): 50-56.
[1]赵京波,赵彤,丘坤元.GRAFT POLYMERIZATION OF ACRYLAMIDE ONTO HOMOPOLYMER OF 5-METHYL-5-HEXEN-2, 4-DIONE INITIATED BY CERIC ION[J].Chinese Journal of Polymer Science,1997,{4}(01):50-56. DOI：

ZHAO Jingbo, ZHAO Tong, QIU Kunyuan. GRAFT POLYMERIZATION OF ACRYLAMIDE ONTO HOMOPOLYMER OF 5-METHYL-5-HEXEN-2, 4-DIONE INITIATED BY CERIC ION*[J]. 1997, 15(1): 50-56. DOI：

摘要

<正> The homopolymerization of 5-methyl-5-hexen-2

4-dione （methacryloylacetone

MAA）

a vinyl monomer having β-diketone group

was carried out in the presence of benzophe-none （BP）/N N-dimenthyl-4-toluidine （DMT） system. Graft polymerization of acrylamideinitiated by ceric ion onto the homopolymer film was investigated and the mechanism ofthe grafting reaction was proposed on the basis of ESR study. The grafted copolymer wascharacterized by means of grafting percentage

water absorption

XPS spectra and scanningelectron photomicrographs.

Abstract

The homopolymerization of 5-methyl-5-hexen-2

4-dione （methacryloylacetone

MAA）

a vinyl monomer having β-diketone group

water absorption

XPS spectra and scanningelectron photomicrographs.

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