SYNTHESIS OF OPTICALLY ACTIVE POLY (N-VINYLCARBAZOLE)S

CHEN Chuanfu; SU Quan; LIU Weihong; CHEN Yongming; XI Fu

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SYNTHESIS OF OPTICALLY ACTIVE POLY (N-VINYLCARBAZOLE)S

Papers | Updated：2021-06-21

- SYNTHESIS OF OPTICALLY ACTIVE POLY (N-VINYLCARBAZOLE)S
- Vol. 14, Issue 4, Pages: 380-384(1996)
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  CLC： TQ317
- Published：20 December 1996
- Accepted：
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[1]陈传福,粟权,刘卫宏,陈永明,习复.SYNTHESIS OF OPTICALLY ACTIVE POLY (N-VINYLCARBAZOLE)S[J].Chinese Journal of Polymer Science,1996,{4}(04):380-384.

CHEN Chuanfu, SU Quan, LIU Weihong, et al. SYNTHESIS OF OPTICALLY ACTIVE POLY (N-VINYLCARBAZOLE)S[J]. 1996, 14(4): 380-384.
[1]陈传福,粟权,刘卫宏,陈永明,习复.SYNTHESIS OF OPTICALLY ACTIVE POLY (N-VINYLCARBAZOLE)S[J].Chinese Journal of Polymer Science,1996,{4}(04):380-384. DOI：

CHEN Chuanfu, SU Quan, LIU Weihong, et al. SYNTHESIS OF OPTICALLY ACTIVE POLY (N-VINYLCARBAZOLE)S[J]. 1996, 14(4): 380-384. DOI：

摘要

正

The organic salts as initiators [A

:Ph

ClO

SbCl

（-）Sp

ClO

and（-）（Sp）

（ClO

）

] and catalysts [A

:（+）CSA

:Ph

（+）CSA

and（-）Sp

（+）CSA] are prepared and characterized by specific rotation. The asymme-trically stereoselective induction of the initiators and catalysts in the polymerization ofN-vinylcarbazole is in an order of A

. The specific rotations ofobtained poly （N-vinylcarbazole ）（PVCZ） generally are in accordance with mentioned order.

Abstract

The organic salts as initiators [A

:Ph

ClO

SbCl

（-）Sp

ClO

and（-）（Sp）

（ClO

）

] and catalysts [A

:（+）CSA

:Ph

（+）CSA

and（-）Sp

. The specific rotations ofobtained poly （N-vinylcarbazole ）（PVCZ） generally are in accordance with mentioned order.

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