EFFECT OF PLASTICIZER ON THE MICROSTRUCTURE OF PS/PVC BLENDS

QIAO Jinliang; D.Vesely

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EFFECT OF PLASTICIZER ON THE MICROSTRUCTURE OF PS/PVC BLENDS

Papers | Updated：2021-06-21

- EFFECT OF PLASTICIZER ON THE MICROSTRUCTURE OF PS/PVC BLENDS
- Vol. 14, Issue 3, Pages: 193-198(1996)
- Affiliations：
  
  1.   Beijing Research Institute of Chemical Industry
  2.   The Ministry of Chemical Industry
  3.   Beijing 100013
  4.   Department of Material Technology
  5.   Brunel University
  6.   Uxbridge
  7.   London   ,UB8 3PH
  8.   UK
- Author bio：
- Funds：
- DOI：
  CLC： TQ325.3
- Published：20 September 1996
- Accepted：
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[1]乔金梁,D.Vesely.EFFECT OF PLASTICIZER ON THE MICROSTRUCTURE OF PS/PVC BLENDS[J].Chinese Journal of Polymer Science,1996,{4}(03):193-198.

QIAO Jinliang, D.Vesely. EFFECT OF PLASTICIZER ON THE MICROSTRUCTURE OF PS/PVC BLENDS[J]. 1996, 14(3): 193-198.
[1]乔金梁,D.Vesely.EFFECT OF PLASTICIZER ON THE MICROSTRUCTURE OF PS/PVC BLENDS[J].Chinese Journal of Polymer Science,1996,{4}(03):193-198. DOI：

QIAO Jinliang, D.Vesely. EFFECT OF PLASTICIZER ON THE MICROSTRUCTURE OF PS/PVC BLENDS[J]. 1996, 14(3): 193-198. DOI：

摘要

<正> In this work

controlling of the particle size of PVC in PS/PVC blends was studied. Itis shown that viscosity ratio and particle size can be changed by adding a third composition

such as plasticizers

and the distribution of the third composition in two phases plays avery important role in controlling viscosity ratio and particle size. When DOP was used asthe plasticizer of PVC in PS/PVC blends

the particle size of PVC could not be reduceddue to the transference of DOP into PS phase. When polycaprolactone （PCL） was usedas the plasticizer of PVC in the same blends

the particle size of PVC could be descreasedobviously because PCL does not migrate to PS phase.

Abstract

In this work

controlling of the particle size of PVC in PS/PVC blends was studied. Itis shown that viscosity ratio and particle size can be changed by adding a third composition

such as plasticizers

and the distribution of the third composition in two phases plays avery important role in controlling viscosity ratio and particle size. When DOP was used asthe plasticizer of PVC in PS/PVC blends

the particle size of PVC could not be reduceddue to the transference of DOP into PS phase. When polycaprolactone （PCL） was usedas the plasticizer of PVC in the same blends

the particle size of PVC could be descreasedobviously because PCL does not migrate to PS phase.

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