SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS

TANG Liming; HUANG Meiyu; JIANG Yingyan

Your Location：

Home >

Browse articles >

SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS

Papers | Updated：2021-06-21

- SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS
- Vol. 14, Issue 3, Pages: 199-204(1996)
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  CLC： O643.3
- Published：20 September 1996
- Accepted：
Scan QR Code
[1]唐黎明,黄美玉,江英彦.SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS[J].Chinese Journal of Polymer Science,1996,{4}(03):199-204.

TANG Liming, HUANG Meiyu, JIANG Yingyan. SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS[J]. 1996, 14(3): 199-204.
[1]唐黎明,黄美玉,江英彦.SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS[J].Chinese Journal of Polymer Science,1996,{4}(03):199-204. DOI：

TANG Liming, HUANG Meiyu, JIANG Yingyan. SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS[J]. 1996, 14(3): 199-204. DOI：

摘要

正

A silica-supported carboxymethylcellulose platinum complex （abbreviated as SiO

-CMC-Pt） has been prepared and characterized by XPS. Its catalytic properties for hydro-genation of aromatic compounds were studied. The results showed that this catalystcould catalyze the hydrogenation of phenol

anisol

p-cresol

benzene and toluene to cyclo-hexanol

cyclohexyl methyl ether

p-methyl cyclohexanol

cyclohexane and methylcyclo-hexane

respectively in 100% yield at 30℃ and 1 atm. In the hydrogenation of phenol

COO/Pt ratio in SiO

-CMC-Pt has much influence on the initial hydrogenation rate andthe selectivity for the intermediate product

cyclohexanone. The highest initial rate andthe highest yield of cyclohexanone both occur at COO/Pt ratio of 6. The complex is stableduring the reaction and can be used repeatedly.

Abstract

A silica-supported carboxymethylcellulose platinum complex （abbreviated as SiO

anisol

p-cresol

benzene and toluene to cyclo-hexanol

cyclohexyl methyl ether

p-methyl cyclohexanol

cyclohexane and methylcyclo-hexane

respectively in 100% yield at 30℃ and 1 atm. In the hydrogenation of phenol

COO/Pt ratio in SiO

-CMC-Pt has much influence on the initial hydrogenation rate andthe selectivity for the intermediate product

cyclohexanone. The highest initial rate andthe highest yield of cyclohexanone both occur at COO/Pt ratio of 6. The complex is stableduring the reaction and can be used repeatedly.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate

Sliding Dynamics of Ring Chain on a Rod-Coil Block Copolymer in Rotaxane

Tunable Circularly Polarized Luminescence of Helical Poly(phenylacetylene)s via Side-chain-to-Backbone Förster Resonance Energy Transfer

Experimental Investigation of Graphene and TiO2 Reinforced Poly(vinyl alcohol)-based Fiber Metal Laminates

Multiple-Responsive Chiral Hydrogels from Helical Dendronized Poly(phenylacetylene)s

Related Author

No data

Related Institution

No data

⁰