STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE OVER A BIDENTATE POLYMER BOUND CIS-DICARBONYLRHODIUM COMPLEX AS CATALYST*

WANG Xiaojun; LIU Zhongyang; PAN Pinglai; YUAN Guoqing

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STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE OVER A BIDENTATE POLYMER BOUND CIS-DICARBONYLRHODIUM COMPLEX AS CATALYST*

Papers | Updated：2021-06-21

- STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE OVER A BIDENTATE POLYMER BOUND CIS-DICARBONYLRHODIUM COMPLEX AS CATALYST*
- Vol. 14, Issue 3, Pages: 233-239(1996)
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Chinese Academy of Sciences
  3.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  CLC： O643.36
- Published：20 September 1996
- Accepted：
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[1]王晓筠,柳忠阳,潘平来,袁国卿.STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE OVER A BIDENTATE POLYMER BOUND CIS-DICARBONYLRHODIUM COMPLEX AS CATALYST[J].Chinese Journal of Polymer Science,1996,{4}(03):233-239.

WANG Xiaojun, LIU Zhongyang, PAN Pinglai, et al. STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE OVER A BIDENTATE POLYMER BOUND CIS-DICARBONYLRHODIUM COMPLEX AS CATALYST*[J]. 1996, 14(3): 233-239.
[1]王晓筠,柳忠阳,潘平来,袁国卿.STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE OVER A BIDENTATE POLYMER BOUND CIS-DICARBONYLRHODIUM COMPLEX AS CATALYST[J].Chinese Journal of Polymer Science,1996,{4}(03):233-239. DOI：

WANG Xiaojun, LIU Zhongyang, PAN Pinglai, et al. STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE OVER A BIDENTATE POLYMER BOUND CIS-DICARBONYLRHODIUM COMPLEX AS CATALYST*[J]. 1996, 14(3): 233-239. DOI：

摘要

<正> Copolymer of 2-vinylpyridine and vinylacetate coordinated with dicarbonylrhodiumused as a catalyst for carbonylation of methanol to acetic acid and anhydride has beenstudied. The structural characteristics of the copolymer ligand and complex

and the in-fluences of the reaction conditions on the carbonylation catalyzed by this polymer complexhave been investigated. In comparison with small molecule catalyst of Rh complex

thebidentate copolymer coordinated complex has better thermal stability. The reactionmechanism of the carbonylation reaction is also illustrated.

Abstract

Copolymer of 2-vinylpyridine and vinylacetate coordinated with dicarbonylrhodiumused as a catalyst for carbonylation of methanol to acetic acid and anhydride has beenstudied. The structural characteristics of the copolymer ligand and complex

and the in-fluences of the reaction conditions on the carbonylation catalyzed by this polymer complexhave been investigated. In comparison with small molecule catalyst of Rh complex

thebidentate copolymer coordinated complex has better thermal stability. The reactionmechanism of the carbonylation reaction is also illustrated.

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