LITHIUM ION CONDUCTING POLYMER ELECTROLYTES BASED ON ALTERNATING MALEIC ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE CHAINS

DING Liming

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LITHIUM ION CONDUCTING POLYMER ELECTROLYTES BASED ON ALTERNATING MALEIC ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE CHAINS

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- LITHIUM ION CONDUCTING POLYMER ELECTROLYTES BASED ON ALTERNATING MALEIC ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE CHAINS
- Vol. 14, Issue 3, Pages: 240-247(1996)
- Affiliations：
  
  1.   Changchun Institute of Applied Chemistry
  2.   Academia Sinica
  3.   Changchun 130022
- Author bio：
- Funds：
- DOI：
  CLC： O631
- Published：20 September 1996
- Accepted：
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[1]丁黎明.LITHIUM ION CONDUCTING POLYMER ELECTROLYTES BASED ON ALTERNATING MALEIC ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE CHAINS[J].Chinese Journal of Polymer Science,1996,{4}(03):240-247.

DING Liming. LITHIUM ION CONDUCTING POLYMER ELECTROLYTES BASED ON ALTERNATING MALEIC ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE CHAINS[J]. 1996, 14(3): 240-247.
[1]丁黎明.LITHIUM ION CONDUCTING POLYMER ELECTROLYTES BASED ON ALTERNATING MALEIC ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE CHAINS[J].Chinese Journal of Polymer Science,1996,{4}(03):240-247. DOI：

DING Liming. LITHIUM ION CONDUCTING POLYMER ELECTROLYTES BASED ON ALTERNATING MALEIC ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE CHAINS[J]. 1996, 14(3): 240-247. DOI：

摘要

正

A comb polymer with oligo-oxyethylene side chains of the type -（CH

O）

was prepared from methyl vinyl ether/maleic anhydride copolymer and poly （ethyleneglycol） methyl ether. The polymer can dissolve LiClO

salt to form homogeneous amor-phous polymer electrolyte. The ac ion conduction was measured using the complex impedancemethod

and conductivities were investigated as functions of temperatures and salt con-centration. The complexes were first found to have two classes of glass transition whichincrease with increasing salt content. The optimum conductivity attained at 25℃ is inthe order of 5.50×10

-6

Scm

-1

. IR spectroscopy was used to study the cation-polymerinteraction.

Abstract

A comb polymer with oligo-oxyethylene side chains of the type -（CH

O）

was prepared from methyl vinyl ether/maleic anhydride copolymer and poly （ethyleneglycol） methyl ether. The polymer can dissolve LiClO

salt to form homogeneous amor-phous polymer electrolyte. The ac ion conduction was measured using the complex impedancemethod

-6

Scm

-1

. IR spectroscopy was used to study the cation-polymerinteraction.

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