CATALYTIC BEHAVIOR OF A SILICA-SUPPORTED POLYTITAZANE-PLATINUM COMPLEX FOR THE HYDROGENATION OF PHENOL

CHEN Chunwei; HUANG Meiyu; JIANG Yingyan

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CATALYTIC BEHAVIOR OF A SILICA-SUPPORTED POLYTITAZANE-PLATINUM COMPLEX FOR THE HYDROGENATION OF PHENOL

Papers | Updated：2021-06-21

- CATALYTIC BEHAVIOR OF A SILICA-SUPPORTED POLYTITAZANE-PLATINUM COMPLEX FOR THE HYDROGENATION OF PHENOL
- Vol. 14, Issue 1, Pages: 26-33(1996)
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  CLC： O631.5
- Published：20 March 1996
- Accepted：
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[1]陈春伟,黄美玉,江英彦.CATALYTIC BEHAVIOR OF A SILICA-SUPPORTED POLYTITAZANE-PLATINUM COMPLEX FOR THE HYDROGENATION OF PHENOL[J].Chinese Journal of Polymer Science,1996,{4}(01):26-33.

CHEN Chunwei, HUANG Meiyu, JIANG Yingyan. CATALYTIC BEHAVIOR OF A SILICA-SUPPORTED POLYTITAZANE-PLATINUM COMPLEX FOR THE HYDROGENATION OF PHENOL[J]. 1996, 14(1): 26-33.
[1]陈春伟,黄美玉,江英彦.CATALYTIC BEHAVIOR OF A SILICA-SUPPORTED POLYTITAZANE-PLATINUM COMPLEX FOR THE HYDROGENATION OF PHENOL[J].Chinese Journal of Polymer Science,1996,{4}(01):26-33. DOI：

CHEN Chunwei, HUANG Meiyu, JIANG Yingyan. CATALYTIC BEHAVIOR OF A SILICA-SUPPORTED POLYTITAZANE-PLATINUM COMPLEX FOR THE HYDROGENATION OF PHENOL[J]. 1996, 14(1): 26-33. DOI：

摘要

<正> A new kind of inorganic polymer

viz. silica-supported polytitazane （Ti-N）

and itsplatinum complex （Ti-N-Pt） were prepared. Cyclohexanone can be obtained in a maximumyield of about 62.2% in the hydrogenation of phenol over Ti-N-Pt at room temperatureunder atmospheric pressure. The effects of mole ratio of N/Pt in the complex

concentrationof the catalyst and reaction temperature on the catalytic activity and selectivity have beenstudied. The complex can be reused several times without loss in its catalytic activity.

Abstract

A new kind of inorganic polymer

viz. silica-supported polytitazane （Ti-N）

concentrationof the catalyst and reaction temperature on the catalytic activity and selectivity have beenstudied. The complex can be reused several times without loss in its catalytic activity.

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