HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS

TANG Liming; HUANG Meiyu; JIANG Yingyan

Your Location：

Home >

Browse articles >

HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS

Papers | Updated：2021-06-21

- HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS
- Vol. 14, Issue 1, Pages: 57-62(1996)
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  CLC： O643.3
- Published：20 March 1996
- Accepted：
Scan QR Code
[1]唐黎明,黄美玉,江英彦.HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS[J].Chinese Journal of Polymer Science,1996(01):57-62.

TANG Liming, HUANG Meiyu, JIANG Yingyan. HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS[J]. 1996, 14(1): 57-62.
[1]唐黎明,黄美玉,江英彦.HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS[J].Chinese Journal of Polymer Science,1996(01):57-62. DOI：

TANG Liming, HUANG Meiyu, JIANG Yingyan. HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS[J]. 1996, 14(1): 57-62. DOI：

摘要

正

A natural polymer catalyst

sillca-supported chitosan palladium complex （abbr. asSiO

-CS-Pd） was found to catalyze the hydrogenation of phenol and cresols to correspond-ing cyclohexanones in high yield and 100% selectivity at 70℃ and 1.01325×10

Pa mildconditions. N/Pd molar ratio in the complex

temperature and solvents have much infiuenceon the reaction. The reactivity order of reactants was found to be: phenol

o-cresol. The catalyst is stable during the reaction and could be repeatedly used for severaltimes without much decrease in its catalytic activity.

Abstract

A natural polymer catalyst

sillca-supported chitosan palladium complex （abbr. asSiO

-CS-Pd） was found to catalyze the hydrogenation of phenol and cresols to correspond-ing cyclohexanones in high yield and 100% selectivity at 70℃ and 1.01325×10

Pa mildconditions. N/Pd molar ratio in the complex

temperature and solvents have much infiuenceon the reaction. The reactivity order of reactants was found to be: phenol

o-cresol. The catalyst is stable during the reaction and could be repeatedly used for severaltimes without much decrease in its catalytic activity.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Enhancing Processability of Phenylethynyl-terminated Imide Oligomers and Properties of Cured Polyimides via ―CF3 Incorporation

Topology-regulated Co-assembly of Single Chain Polymer Nanoparticles and Block Copolymers into Hierarchical Micelle@Vesicle Composite Structures

Multiple-Responsive Chiral Hydrogels from Helical Dendronized Poly(phenylacetylene)s

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Alternating Poly(ether-alt-ester)s with High Glass Transition Temperature Enabled by Rotationally Constrained Biaryl Units

Related Author

No data

Related Institution

No data

⁰