THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*

WAN Meixiang; Li Ming; MI Xin; JIANG Qian; YE Peixian

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THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*

Papers | Updated：2021-06-21

- THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*
- Vol. 14, Issue 1, Pages: 80-85(1996)
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
  4.   Institute of Physics
- Author bio：
- Funds：
- DOI：
  CLC： O631.4
- Published：20 March 1996
- Accepted：
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[1]万梅香,李明,米辛,姜谦,叶佩弦.THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID[J].Chinese Journal of Polymer Science,1996,{4}(01):80-85.

WAN Meixiang, Li Ming, MI Xin, et al. THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*[J]. 1996, 14(1): 80-85.
[1]万梅香,李明,米辛,姜谦,叶佩弦.THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID[J].Chinese Journal of Polymer Science,1996,{4}(01):80-85. DOI：

WAN Meixiang, Li Ming, MI Xin, et al. THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*[J]. 1996, 14(1): 80-85. DOI：

摘要

正

The fully oxidized state of polyaniline （PANI）

pernigraniline （PN）

was synthesizedby oxidation of the emeraldine base form of PANI dissolved in NMP solvent with m-chloroperoxybenzoic acid. The resulted PN was characterized by FTIR and UV-Visiblespectra. The third-order nonlinear optical properties of PN in concentrated sulfuric acid（PN/H

） were measured by a degenerated four wave mixing （DFWM） method. The re-sults obtained suggest that the soliton-pair intermediate state associated with thedegenerated state does not play a major role in the third order nonlinear optical prop-erties of PANI.

Abstract

The fully oxidized state of polyaniline （PANI）

pernigraniline （PN）

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