GRAFT COPOLYMERIZATION OF VINYL MONOMERS ONTO STARCH INITIATED BY TRANSITION METAL-THIOUREA REDOX SYSTEMS

GAO Jianping; TIAN Ruchuan; ZHANG Liming

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GRAFT COPOLYMERIZATION OF VINYL MONOMERS ONTO STARCH INITIATED BY TRANSITION METAL-THIOUREA REDOX SYSTEMS

Papers | Updated：2021-06-21

- GRAFT COPOLYMERIZATION OF VINYL MONOMERS ONTO STARCH INITIATED BY TRANSITION METAL-THIOUREA REDOX SYSTEMS
- Vol. 14, Issue 2, Pages: 163-171(1996)
- Affiliations：
  
  1.   Department of Chemistry
  2.   Tianjin University
  3.   Tianjin 300072
- Author bio：
- Funds：
- DOI：
  CLC： TQ316.6
- Published：20 June 1996
- Accepted：
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[1]高建平,田汝川,张黎明.GRAFT COPOLYMERIZATION OF VINYL MONOMERS ONTO STARCH INITIATED BY TRANSITION METAL-THIOUREA REDOX SYSTEMS[J].Chinese Journal of Polymer Science,1996,{4}(02):163-171.

GAO Jianping, TIAN Ruchuan, ZHANG Liming. GRAFT COPOLYMERIZATION OF VINYL MONOMERS ONTO STARCH INITIATED BY TRANSITION METAL-THIOUREA REDOX SYSTEMS[J]. 1996, 14(2): 163-171.
[1]高建平,田汝川,张黎明.GRAFT COPOLYMERIZATION OF VINYL MONOMERS ONTO STARCH INITIATED BY TRANSITION METAL-THIOUREA REDOX SYSTEMS[J].Chinese Journal of Polymer Science,1996,{4}(02):163-171. DOI：

GAO Jianping, TIAN Ruchuan, ZHANG Liming. GRAFT COPOLYMERIZATION OF VINYL MONOMERS ONTO STARCH INITIATED BY TRANSITION METAL-THIOUREA REDOX SYSTEMS[J]. 1996, 14(2): 163-171. DOI：

摘要

正

In this paper

the capabilities of grafting acrylonitrile （AN） onto starch initiatedby Fe（III）-TU

V（V）-TU

Cr（VI）-TU

Mn（VII）-TU redox systems were compared in thepresence of sulfuric acid of different concentrations. It was shown that the grafting capabili-ty of Mn（VII）-TU is the highest in these initiating systems. Using Mn (VII-TU as initia-tor

the effects of various acids （HClO

HNO

HCl） on the graft copolymerizationof acrylonitrile onto starch were discussed

and the capabilities of graft copolymerizationof methyl methacrylate （MMA）

acrylamide （AM）

acrylic acid （AA） onto starch wereinvestigated. The experimental results show that the order of the influences of differentacids is HClO

HNO

HCl

and the order of grafting capabilities of differentmonomers grafted onto starch is MMA

AA. The structure and morphology ofgraft copolymers were studied with infrared spectroscopy and scanning electron microscopy.The size

shape and roughness of surface of the grafted starch granules are changed aftergrafting.

Abstract

In this paper

the capabilities of grafting acrylonitrile （AN） onto starch initiatedby Fe（III）-TU

V（V）-TU

Cr（VI）-TU

the effects of various acids （HClO

HNO

HCl） on the graft copolymerizationof acrylonitrile onto starch were discussed

and the capabilities of graft copolymerizationof methyl methacrylate （MMA）

acrylamide （AM）

acrylic acid （AA） onto starch wereinvestigated. The experimental results show that the order of the influences of differentacids is HClO

HNO

HCl

and the order of grafting capabilities of differentmonomers grafted onto starch is MMA

AA. The structure and morphology ofgraft copolymers were studied with infrared spectroscopy and scanning electron microscopy.The size

shape and roughness of surface of the grafted starch granules are changed aftergrafting.

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